Construction of fused bicyclo-[5.3.0]decane and -[5.4.0]undecane ring skeletons via sequential additions of nucleophiles to tricarbonyltropyliumchromium tetrafluroborate

Ming Chang P. Yeh; Chong Nan Chuang

doi:10.1039/C39940000703

Construction of fused bicyclo-[5.3.0]decane and -[5.4.0]undecane ring skeletons via sequential additions of nucleophiles to tricarbonyltropyliumchromium tetrafluroborate

Ming Chang P. Yeh^*
, Chong Nan Chuang

^*此作品的通信作者

化學系

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

14 引文斯高帕斯（Scopus）

摘要

The addition of a variety of the highly functionalized zinc-copper reagents RCu(CN)ZnI to the title cation gives (η⁶-cyclohepta-1,3,5- triene)Cr(CO)₃ complexes with a functionalized side chain at the C-7 position of the ring: intramolecular cyclisation of ester-substituted adducts using lithium diisopropylamide generates fused bicyclo-[5.3.0]decane and -[5.4.0]undecane derivatives.

原文	英語
頁（從 - 到）	703-704
頁數	2
期刊	Journal of the Chemical Society D: Chemical Communications
發行號	6
DOIs	https://doi.org/10.1039/C39940000703
出版狀態	已發佈 - 1994

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分子醫學

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10.1039/C39940000703

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abstract = "The addition of a variety of the highly functionalized zinc-copper reagents RCu(CN)ZnI to the title cation gives (η6-cyclohepta-1,3,5- triene)Cr(CO)3 complexes with a functionalized side chain at the C-7 position of the ring: intramolecular cyclisation of ester-substituted adducts using lithium diisopropylamide generates fused bicyclo-[5.3.0]decane and -[5.4.0]undecane derivatives.",

author = "Yeh, \{Ming Chang P.\} and Chuang, \{Chong Nan\}",

year = "1994",

doi = "10.1039/C39940000703",

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journal = "Journal of the Chemical Society D: Chemical Communications",

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AU - Yeh, Ming Chang P.

AU - Chuang, Chong Nan

PY - 1994

Y1 - 1994

N2 - The addition of a variety of the highly functionalized zinc-copper reagents RCu(CN)ZnI to the title cation gives (η6-cyclohepta-1,3,5- triene)Cr(CO)3 complexes with a functionalized side chain at the C-7 position of the ring: intramolecular cyclisation of ester-substituted adducts using lithium diisopropylamide generates fused bicyclo-[5.3.0]decane and -[5.4.0]undecane derivatives.

AB - The addition of a variety of the highly functionalized zinc-copper reagents RCu(CN)ZnI to the title cation gives (η6-cyclohepta-1,3,5- triene)Cr(CO)3 complexes with a functionalized side chain at the C-7 position of the ring: intramolecular cyclisation of ester-substituted adducts using lithium diisopropylamide generates fused bicyclo-[5.3.0]decane and -[5.4.0]undecane derivatives.

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UR - https://www.scopus.com/pages/publications/37049085532#tab=citedBy

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JO - Journal of the Chemical Society D: Chemical Communications

JF - Journal of the Chemical Society D: Chemical Communications

IS - 6

ER -

Construction of fused bicyclo-[5.3.0]decane and -[5.4.0]undecane ring skeletons via sequential additions of nucleophiles to tricarbonyltropyliumchromium tetrafluroborate

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