Construction of fused bicyclo-[5.3.0]decane and -[5.4.0]undecane ring skeletons via sequential additions of nucleophiles to tricarbonyltropyliumchromium tetrafluroborate

Ming-Chang P. Yeh, Chong Nan Chuang

研究成果: 雜誌貢獻文章

13 引文 斯高帕斯(Scopus)

摘要

The addition of a variety of the highly functionalized zinc-copper reagents RCu(CN)ZnI to the title cation gives (η 6 -cyclohepta-1,3,5- triene)Cr(CO) 3 complexes with a functionalized side chain at the C-7 position of the ring: intramolecular cyclisation of ester-substituted adducts using lithium diisopropylamide generates fused bicyclo-[5.3.0]decane and -[5.4.0]undecane derivatives.

原文英語
頁(從 - 到)703-704
頁數2
期刊Journal of the Chemical Society, Chemical Communications
發行號6
DOIs
出版狀態已發佈 - 1994 十二月 1

ASJC Scopus subject areas

  • Molecular Medicine

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