Completely diastereoselective tricarbonyliron complexation reactions of chiral dienes

Ming Shan Tsai; U. Narasimha Rao; Peng Yu Hsueh; Ming Chang P. Yeh

doi:10.1021/om000719f

Completely diastereoselective tricarbonyliron complexation reactions of chiral dienes

Ming Shan Tsai
, U. Narasimha Rao
, Peng Yu Hsueh
, Ming Chang P. Yeh

化學系

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

9 引文斯高帕斯（Scopus）

摘要

Complexation of cylic and acyclic dienes, carrying a (1S)-(+)-ketopinoxy as the chiral auxiliary, with nonacarbonyldiiron proceeds in a completely diastereoselective fashion to afford diene-iron complexes in moderate yields. When (1R)-(-)-ketopinoxy was used as the chiral auxiliary, the opposite enantioisomeric complexes are isolated as a single diastereomer in comparable yield and specific rotation in each case. The stereochemistry of chiral cyclic and acyclic diene-iron complexes is determined by single-crystal X-ray methods.

原文	英語
頁（從 - 到）	289-295
頁數	7
期刊	Organometallics
卷	20
發行號	2
DOIs	https://doi.org/10.1021/om000719f
出版狀態	已發佈 - 2001 1月

ASJC Scopus subject areas

物理與理論化學
有機化學
無機化學

存取文件

10.1021/om000719f

其它文件與鏈接

CCDC 159510: Experimental Crystal Structure Determination
Tsai, M.-S. (Creator), Narasimha Rao, R. U. (Contributor), Hsueh, P.-Y. (Creator) & Yeh, M. C. P. (Creator), Unknown Publisher, 2001
DOI: 10.5517/cc5bzhy, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc5bzhy&sid=DataCite
資料集: Dataset
CCDC 159511: Experimental Crystal Structure Determination
Tsai, M.-S. (Creator), Narasimha Rao, R. U. (Contributor), Hsueh, P.-Y. (Creator) & Yeh, M. C. P. (Creator), Unknown Publisher, 2001
DOI: 10.5517/cc5bzjz, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc5bzjz&sid=DataCite
資料集: Dataset

引用此

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abstract = "Complexation of cylic and acyclic dienes, carrying a (1S)-(+)-ketopinoxy as the chiral auxiliary, with nonacarbonyldiiron proceeds in a completely diastereoselective fashion to afford diene-iron complexes in moderate yields. When (1R)-(-)-ketopinoxy was used as the chiral auxiliary, the opposite enantioisomeric complexes are isolated as a single diastereomer in comparable yield and specific rotation in each case. The stereochemistry of chiral cyclic and acyclic diene-iron complexes is determined by single-crystal X-ray methods.",

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year = "2001",

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doi = "10.1021/om000719f",

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AU - Tsai, Ming Shan

AU - Narasimha Rao, U.

AU - Hsueh, Peng Yu

AU - Yeh, Ming Chang P.

PY - 2001/1

Y1 - 2001/1

N2 - Complexation of cylic and acyclic dienes, carrying a (1S)-(+)-ketopinoxy as the chiral auxiliary, with nonacarbonyldiiron proceeds in a completely diastereoselective fashion to afford diene-iron complexes in moderate yields. When (1R)-(-)-ketopinoxy was used as the chiral auxiliary, the opposite enantioisomeric complexes are isolated as a single diastereomer in comparable yield and specific rotation in each case. The stereochemistry of chiral cyclic and acyclic diene-iron complexes is determined by single-crystal X-ray methods.

AB - Complexation of cylic and acyclic dienes, carrying a (1S)-(+)-ketopinoxy as the chiral auxiliary, with nonacarbonyldiiron proceeds in a completely diastereoselective fashion to afford diene-iron complexes in moderate yields. When (1R)-(-)-ketopinoxy was used as the chiral auxiliary, the opposite enantioisomeric complexes are isolated as a single diastereomer in comparable yield and specific rotation in each case. The stereochemistry of chiral cyclic and acyclic diene-iron complexes is determined by single-crystal X-ray methods.

UR - https://www.scopus.com/pages/publications/0035125189

UR - https://www.scopus.com/pages/publications/0035125189#tab=citedBy

U2 - 10.1021/om000719f

DO - 10.1021/om000719f

M3 - Article

AN - SCOPUS:0035125189

SN - 0276-7333

VL - 20

SP - 289

EP - 295

JO - Organometallics

JF - Organometallics

IS - 2

ER -

Completely diastereoselective tricarbonyliron complexation reactions of chiral dienes

摘要

ASJC Scopus subject areas

存取文件

其它文件與鏈接

指紋

資料集

CCDC 159510: Experimental Crystal Structure Determination

CCDC 159511: Experimental Crystal Structure Determination

引用此