Chlorido[hydridotris(pyrazol-1-yl-κN2)borato](1H-pyrazole- κN2)(triphenyl-phosphine-κP)ruthenium(II)

Chiung Cheng Huang, Han Gung Chen, Yih Hsing Lo, Li Sheng Hsu, Chia Her Lin

研究成果: 雜誌貢獻期刊論文同行評審

1 引文 斯高帕斯(Scopus)

摘要

In the title compound, [Ru(C9H10BN 6)Cl(C3H4N2)(C18H 15P)], the RuII atom is coordinated by an N,N′,N′′-tridentate hydrido-trispyrazolylborate (Tp) ligand, a pyrazole (HPz) molecule, a chloride ion and a triphenyl-phosphine ligand, resulting in a distorted RuClPN4 octa-hedral coordination for the metal ion: the tridentate N atoms occupy one octa-hedral face and the Cl and P atoms are cis. One of the phenyl rings is disordered over two orientations in a 0.547 (10):0.453 (10) ratio, and a weak intra-molecular N-H⋯Cl hydrogen bond generates an S(5) ring.

原文英語
頁(從 - 到)m795-m796
期刊Acta Crystallographica Section E: Structure Reports Online
66
發行號7
DOIs
出版狀態已發佈 - 2010
對外發佈

ASJC Scopus subject areas

  • 化學 (全部)
  • 材料科學(全部)
  • 凝聚態物理學

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