Characterizing xBa (Mg1/3Ta2/3)O3+ (1-x) Ba (Mg1/3Nb2/3)O3 microwave ceramics using extended x-ray absorption fine structure method

P. J. Chang; C. T. Chia; I. N. Lin; J. F. Lee; C. M. Lin; K. T. Wu

doi:10.1063/1.2213514

Characterizing xBa (Mg_1/3Ta_2/3)O₃+ (1-x) Ba (Mg_1/3Nb_2/3)O₃ microwave ceramics using extended x-ray absorption fine structure method

P. J. Chang, C. T. Chia^*, I. N. Lin, J. F. Lee, C. M. Lin, K. T. Wu

^*此作品的通信作者

物理學系

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

11 引文斯高帕斯（Scopus）

摘要

The structures of Ta O6 and Nb O6 oxygen octahedra in xBa (Mg13 Ta23) O3 + (1-x) Ba (Mg13 Nb23) O3 perovskite ceramics with x=0, 0.25, 0.50, 0.75, and 1.0 were investigated by the extended x-ray absorption fine structure method. The decline in the microwave dielectric constant as x increases is caused mainly by the decrease of the mean volume of the oxygen octahedra, regardless of the 1:2 ordered structure and the distortion of the oxygen octahedron. The low Qf values of the Ta O6 and Nb O6 mixed samples are caused by not only the degrading of the 1:2 ordered structure but also the distortion of oxygen octahedral cages.

原文	英語
文章編號	242907
期刊	Applied Physics Letters
卷	88
發行號	24
DOIs	https://doi.org/10.1063/1.2213514
出版狀態	已發佈 - 2006 6月 12

ASJC Scopus subject areas

物理與天文學（雜項）

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10.1063/1.2213514

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@article{c5860dad195b481f81a7ce766434e293,

title = "Characterizing xBa (Mg1/3Ta2/3)O3+ (1-x) Ba (Mg1/3Nb2/3)O3 microwave ceramics using extended x-ray absorption fine structure method",

abstract = "The structures of Ta O6 and Nb O6 oxygen octahedra in xBa (Mg13 Ta23) O3 + (1-x) Ba (Mg13 Nb23) O3 perovskite ceramics with x=0, 0.25, 0.50, 0.75, and 1.0 were investigated by the extended x-ray absorption fine structure method. The decline in the microwave dielectric constant as x increases is caused mainly by the decrease of the mean volume of the oxygen octahedra, regardless of the 1:2 ordered structure and the distortion of the oxygen octahedron. The low Qf values of the Ta O6 and Nb O6 mixed samples are caused by not only the degrading of the 1:2 ordered structure but also the distortion of oxygen octahedral cages.",

author = "Chang, {P. J.} and Chia, {C. T.} and Lin, {I. N.} and Lee, {J. F.} and Lin, {C. M.} and Wu, {K. T.}",

note = "Funding Information: The authors would like to thank the National Science Council of the Republic of China, Taiwan, for financially supporting this research under Contract No. NSC 94-2112-M-003-007. ",

year = "2006",

month = jun,

day = "12",

doi = "10.1063/1.2213514",

language = "English",

volume = "88",

journal = "Applied Physics Letters",

issn = "0003-6951",

publisher = "American Institute of Physics Publising LLC",

number = "24",

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TY - JOUR

T1 - Characterizing xBa (Mg1/3Ta2/3)O3+ (1-x) Ba (Mg1/3Nb2/3)O3 microwave ceramics using extended x-ray absorption fine structure method

AU - Chang, P. J.

AU - Chia, C. T.

AU - Lin, I. N.

AU - Lee, J. F.

AU - Lin, C. M.

AU - Wu, K. T.

N1 - Funding Information: The authors would like to thank the National Science Council of the Republic of China, Taiwan, for financially supporting this research under Contract No. NSC 94-2112-M-003-007.

PY - 2006/6/12

Y1 - 2006/6/12

N2 - The structures of Ta O6 and Nb O6 oxygen octahedra in xBa (Mg13 Ta23) O3 + (1-x) Ba (Mg13 Nb23) O3 perovskite ceramics with x=0, 0.25, 0.50, 0.75, and 1.0 were investigated by the extended x-ray absorption fine structure method. The decline in the microwave dielectric constant as x increases is caused mainly by the decrease of the mean volume of the oxygen octahedra, regardless of the 1:2 ordered structure and the distortion of the oxygen octahedron. The low Qf values of the Ta O6 and Nb O6 mixed samples are caused by not only the degrading of the 1:2 ordered structure but also the distortion of oxygen octahedral cages.

AB - The structures of Ta O6 and Nb O6 oxygen octahedra in xBa (Mg13 Ta23) O3 + (1-x) Ba (Mg13 Nb23) O3 perovskite ceramics with x=0, 0.25, 0.50, 0.75, and 1.0 were investigated by the extended x-ray absorption fine structure method. The decline in the microwave dielectric constant as x increases is caused mainly by the decrease of the mean volume of the oxygen octahedra, regardless of the 1:2 ordered structure and the distortion of the oxygen octahedron. The low Qf values of the Ta O6 and Nb O6 mixed samples are caused by not only the degrading of the 1:2 ordered structure but also the distortion of oxygen octahedral cages.

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DO - 10.1063/1.2213514

M3 - Article

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SN - 0003-6951

VL - 88

JO - Applied Physics Letters

JF - Applied Physics Letters

IS - 24

M1 - 242907

ER -

Characterizing xBa (Mg1/3Ta2/3)O3+ (1-x) Ba (Mg1/3Nb2/3)O3 microwave ceramics using extended x-ray absorption fine structure method

摘要

ASJC Scopus subject areas

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指紋

引用此

Characterizing xBa (Mg_1/3Ta_2/3)O₃+ (1-x) Ba (Mg_1/3Nb_2/3)O₃ microwave ceramics using extended x-ray absorption fine structure method