TY - JOUR
T1 - Carbonization and oxidation of metal-organic frameworks based on 1,4-naphthalene dicarboxylates
AU - Chen, Jiun Jen
AU - Chen, Ya Ting
AU - Senthil Raja, Duraisamy
AU - Kang, Yu Hao
AU - Tseng, Pen Chang
AU - Lin, Chia Her
N1 - Publisher Copyright:
© 2015 National Institute for Materials Science.
PY - 2015/10/6
Y1 - 2015/10/6
N2 - Three new isostructural metal-organic frameworks (MOFs), [V(OH)(NDC)] (1), [Cr(OH)(NDC)] (2), and [Ga(OH)(NDC)] (3) have been synthesized hydrothermally using 1,4-naphthalene dicarboxylate (NDC) as the linker. These MOFs (1, 2 and 3) have been used as a template for the synthesis of metal-oxide-inserted nanoporous carbon materials. The newly synthesized MOFs and the resulting porous carbon hybrid functional materials have been characterized using powder x-ray diffraction, scanning electron microscopy, transmission electron microscopy, and energy dispersive x-ray spectroscopic analysis. Results show that compounds 2 and 3 form their respective metal oxide nanoparticles on the surface of the carbon materials during carbonization at 800 °C. The gas sorption properties of the new MOFs and their corresponding carbon frameworks have been reported.
AB - Three new isostructural metal-organic frameworks (MOFs), [V(OH)(NDC)] (1), [Cr(OH)(NDC)] (2), and [Ga(OH)(NDC)] (3) have been synthesized hydrothermally using 1,4-naphthalene dicarboxylate (NDC) as the linker. These MOFs (1, 2 and 3) have been used as a template for the synthesis of metal-oxide-inserted nanoporous carbon materials. The newly synthesized MOFs and the resulting porous carbon hybrid functional materials have been characterized using powder x-ray diffraction, scanning electron microscopy, transmission electron microscopy, and energy dispersive x-ray spectroscopic analysis. Results show that compounds 2 and 3 form their respective metal oxide nanoparticles on the surface of the carbon materials during carbonization at 800 °C. The gas sorption properties of the new MOFs and their corresponding carbon frameworks have been reported.
KW - metal oxide nanoparticle
KW - metal-organic frameworks
KW - nanoporous carbon
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U2 - 10.1088/1468-6996/16/5/054203
DO - 10.1088/1468-6996/16/5/054203
M3 - Article
AN - SCOPUS:84947262140
SN - 1468-6996
VL - 16
JO - Science and Technology of Advanced Materials
JF - Science and Technology of Advanced Materials
IS - 5
M1 - 054203
ER -