Bis[2-(pyrimidin-2-ylamino)pyrimidin-ium] hexa-molybdate

Chun Wei Yeh, Chia Her Lin*, Jhy Der Chen

*此作品的通信作者

研究成果: 雜誌貢獻期刊論文同行評審

1 引文 斯高帕斯(Scopus)

摘要

The title compound, (C8H8N5)2[Mo6O19], was prepared by reaction of Mo(CO)6 and dipyrimidylamine in refluxing toluene. The hexa-nuclear polyoxomolybdate anions lie on centres of inversion. Each 2-(pyrimidin-2-ylamino)pyrimidinium cation forms an intra-molecular N - H⋯N hydrogen bond and the cations are linked through self-complementary pairs of N - H⋯N hydrogen bonds into dimers across centres of inversion. The cations and anions are inter-linked through C - H⋯O contacts.

原文英語
頁(從 - 到)m41
期刊Acta Crystallographica Section E: Structure Reports Online
64
發行號1
DOIs
出版狀態已發佈 - 2008
對外發佈

ASJC Scopus subject areas

  • 一般化學
  • 一般材料科學
  • 凝聚態物理學

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