Bis[-2-(2H-benzotriazol-2-yl)-4-methyl-phenolato]bis-[dimethyl- aluminium(III)]

Chen Yu Li; Chia Her Lin; Bao Tsan Ko

doi:10.1107/S1600536809018492

Bis[-2-(2H-benzotriazol-2-yl)-4-methyl-phenolato]bis-[dimethyl- aluminium(III)]

Chen Yu Li
, Chia Her Lin
, Bao Tsan Ko^*

^*此作品的通信作者

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

6 引文斯高帕斯（Scopus）

摘要

The title complex, [A_l2(CH₃)₄(C ₁₃H₁₀N₃O)₂], is dimeric, bridged through the O atoms of the phenolate anions. The asymmetric unit contains one half of the mol-ecule and there is a crystallographic inversion centre in this mol-ecule. Each Al atom is penta-coordinated by one N atom and two bridging O atoms of two N,O-bidentate benzotriazolylphenolate ligands and by two C atoms from two methyl groups, forming a distorted trigonal-bipyramidal environment.

原文	英語
頁（從 - 到）	m670
期刊	Acta Crystallographica Section E: Structure Reports Online
卷	65
發行號	6
DOIs	https://doi.org/10.1107/S1600536809018492
出版狀態	已發佈 - 2009
對外發佈	是

ASJC Scopus subject areas

一般化學
一般材料科學
凝聚態物理學

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10.1107/S1600536809018492

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title = "Bis[-2-(2H-benzotriazol-2-yl)-4-methyl-phenolato]bis-[dimethyl- aluminium(III)]",

abstract = "The title complex, [Al2(CH3)4(C 13H10N3O)2], is dimeric, bridged through the O atoms of the phenolate anions. The asymmetric unit contains one half of the mol-ecule and there is a crystallographic inversion centre in this mol-ecule. Each Al atom is penta-coordinated by one N atom and two bridging O atoms of two N,O-bidentate benzotriazolylphenolate ligands and by two C atoms from two methyl groups, forming a distorted trigonal-bipyramidal environment.",

author = "Li, \{Chen Yu\} and Lin, \{Chia Her\} and Ko, \{Bao Tsan\}",

year = "2009",

doi = "10.1107/S1600536809018492",

language = "English",

volume = "65",

pages = "m670",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

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TY - JOUR

T1 - Bis[-2-(2H-benzotriazol-2-yl)-4-methyl-phenolato]bis-[dimethyl- aluminium(III)]

AU - Li, Chen Yu

AU - Lin, Chia Her

AU - Ko, Bao Tsan

PY - 2009

Y1 - 2009

N2 - The title complex, [Al2(CH3)4(C 13H10N3O)2], is dimeric, bridged through the O atoms of the phenolate anions. The asymmetric unit contains one half of the mol-ecule and there is a crystallographic inversion centre in this mol-ecule. Each Al atom is penta-coordinated by one N atom and two bridging O atoms of two N,O-bidentate benzotriazolylphenolate ligands and by two C atoms from two methyl groups, forming a distorted trigonal-bipyramidal environment.

AB - The title complex, [Al2(CH3)4(C 13H10N3O)2], is dimeric, bridged through the O atoms of the phenolate anions. The asymmetric unit contains one half of the mol-ecule and there is a crystallographic inversion centre in this mol-ecule. Each Al atom is penta-coordinated by one N atom and two bridging O atoms of two N,O-bidentate benzotriazolylphenolate ligands and by two C atoms from two methyl groups, forming a distorted trigonal-bipyramidal environment.

UR - https://www.scopus.com/pages/publications/67649834589

UR - https://www.scopus.com/pages/publications/67649834589#tab=citedBy

U2 - 10.1107/S1600536809018492

DO - 10.1107/S1600536809018492

M3 - Article

AN - SCOPUS:67649834589

SN - 1600-5368

VL - 65

SP - m670

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 6

ER -

Bis[-2-(2H-benzotriazol-2-yl)-4-methyl-phenolato]bis-[dimethyl- aluminium(III)]

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ASJC Scopus subject areas

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