TY - JOUR
T1 - Azido(benzonitrile-κN)[hydridotris(pyrazol-1-yl-κN 2)borato](triphenyl-phosphine-κP)ruthenium(II)
AU - Huang, Chiung Cheng
AU - Chen, Han Gung
AU - Lo, Yih Hsing
AU - Lai, Wen Rong
AU - Lin, Chia Her
PY - 2010
Y1 - 2010
N2 - Facile ligand substitution is observed when the ruthenium-azide complex, [RuN3(Tp)(PPh3)2] [Tp,HB(pz)3, pz = pyrazolyl, PPh3 = triphenyl-phosphine] is treated with benzo-nitrile, yielding the title compound, [Ru(C9H10BN 6)(N3)(C7H5N)(C18H 15P)]. The asymmetric unit contains two crystallographically independent molecules. In each one, the RuII atom is six-coordinated in a distorted octa-hedral geometry by five N atoms from an htpb ligand, an azide ligand and a benzonitrile ligand and one P atom from a triphenyl-phosphine (tpp) ligand. The azide group is almost linear and is coordinated to Ru with an average Ru-N-N angle of 124.9 (3)°.
AB - Facile ligand substitution is observed when the ruthenium-azide complex, [RuN3(Tp)(PPh3)2] [Tp,HB(pz)3, pz = pyrazolyl, PPh3 = triphenyl-phosphine] is treated with benzo-nitrile, yielding the title compound, [Ru(C9H10BN 6)(N3)(C7H5N)(C18H 15P)]. The asymmetric unit contains two crystallographically independent molecules. In each one, the RuII atom is six-coordinated in a distorted octa-hedral geometry by five N atoms from an htpb ligand, an azide ligand and a benzonitrile ligand and one P atom from a triphenyl-phosphine (tpp) ligand. The azide group is almost linear and is coordinated to Ru with an average Ru-N-N angle of 124.9 (3)°.
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U2 - 10.1107/S1600536810021513
DO - 10.1107/S1600536810021513
M3 - Article
AN - SCOPUS:77954407964
SN - 1600-5368
VL - 66
SP - m864
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 7
ER -