Asymmetric Organocatalytic Reactions of Activated Racemic Allenes

Paru Jamwal, Himani Vaid, Gunda Ananda Rao, Ramani Gurubrahamam*, Kwunmin Chen*

*此作品的通信作者

研究成果: 雜誌貢獻回顧評介論文同行評審

3 引文 斯高帕斯(Scopus)

摘要

Asymmetric organocatalytic reactions of various electron-deficient racemic allenes with a wide variety of nucleophiles and electrophiles were reviewed. The literature on enantioselective functionalization of allenes that employs chiral phosphine, amine, phase transfer, bifunctional, and Brønsted acid catalysis is presented along with the mechanisms. In addition, the review emphasizes methods of obtaining enantioenriched allenes from racemic allenes via organocatalytic (dynamic) kinetic resolution techniques. The synthetic utility of the developed methodologies toward the target-orientated biologically active molecules is narrated along with the examples.

原文英語
文章編號e202200622
期刊Asian Journal of Organic Chemistry
11
發行號12
DOIs
出版狀態已發佈 - 2022 12月

ASJC Scopus subject areas

  • 有機化學

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