Asymmetric Organocatalysis of Activated Alkynes and Enynes

Akashdeep Sharma; Koppanathi Nagaraju; Gunda Ananda Rao; Ramani Gurubrahamam; Kwunmin Chen

doi:10.1002/ajoc.202100252

Asymmetric Organocatalysis of Activated Alkynes and Enynes

Akashdeep Sharma, Koppanathi Nagaraju, Gunda Ananda Rao, Ramani Gurubrahamam^*, Kwunmin Chen^*

^*此作品的通信作者

化學系

研究成果: 雜誌貢獻 › 回顧評介論文 › 同行評審

12 引文斯高帕斯（Scopus）

摘要

Enantioselective organocatalytic protocols for the functionalization of electron-deficient internal alkynes and enynes are reviewed. This review focuses on the applicability of activated conjugated π-systems in asymmetric synthesis for providing diversified chiral entities under metal-free reaction conditions. Various organocatalytic strategies with different catalytic modes are demonstrated.

原文	英語
頁（從 - 到）	1567-1579
頁數	13
期刊	Asian Journal of Organic Chemistry
卷	10
發行號	7
DOIs	https://doi.org/10.1002/ajoc.202100252
出版狀態	已發佈 - 2021 7月

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有機化學

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10.1002/ajoc.202100252

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title = "Asymmetric Organocatalysis of Activated Alkynes and Enynes",

abstract = "Enantioselective organocatalytic protocols for the functionalization of electron-deficient internal alkynes and enynes are reviewed. This review focuses on the applicability of activated conjugated π-systems in asymmetric synthesis for providing diversified chiral entities under metal-free reaction conditions. Various organocatalytic strategies with different catalytic modes are demonstrated.",

keywords = "Alkynals, Alkynes, Alkynoates, Alkynones, Enantioselective, Enynes, Enynones, Organocatalysis",

author = "Akashdeep Sharma and Koppanathi Nagaraju and Rao, {Gunda Ananda} and Ramani Gurubrahamam and Kwunmin Chen",

note = "Publisher Copyright: {\textcopyright} 2021 Wiley-VCH GmbH.",

year = "2021",

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doi = "10.1002/ajoc.202100252",

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AU - Sharma, Akashdeep

AU - Nagaraju, Koppanathi

AU - Rao, Gunda Ananda

AU - Gurubrahamam, Ramani

AU - Chen, Kwunmin

PY - 2021/7

Y1 - 2021/7

N2 - Enantioselective organocatalytic protocols for the functionalization of electron-deficient internal alkynes and enynes are reviewed. This review focuses on the applicability of activated conjugated π-systems in asymmetric synthesis for providing diversified chiral entities under metal-free reaction conditions. Various organocatalytic strategies with different catalytic modes are demonstrated.

AB - Enantioselective organocatalytic protocols for the functionalization of electron-deficient internal alkynes and enynes are reviewed. This review focuses on the applicability of activated conjugated π-systems in asymmetric synthesis for providing diversified chiral entities under metal-free reaction conditions. Various organocatalytic strategies with different catalytic modes are demonstrated.

KW - Alkynals

KW - Alkynes

KW - Alkynoates

KW - Alkynones

KW - Enantioselective

KW - Enynes

KW - Enynones

KW - Organocatalysis

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U2 - 10.1002/ajoc.202100252

DO - 10.1002/ajoc.202100252

M3 - Review article

AN - SCOPUS:85107285079

SN - 2193-5807

VL - 10

SP - 1567

EP - 1579

JO - Asian Journal of Organic Chemistry

JF - Asian Journal of Organic Chemistry

IS - 7

ER -

Asymmetric Organocatalysis of Activated Alkynes and Enynes

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