Assembly of a water-insoluble strontium metal-organic framework with luminescent properties

Sheng Han Lo; Hsin Kuan Liu; Jun Xiang Zhan; Wei Cheng Lin; Ching Che Kao; Chia Her Lin; Vítězslav Zima

doi:10.1016/j.inoche.2011.06.017

Assembly of a water-insoluble strontium metal-organic framework with luminescent properties

Sheng Han Lo, Hsin Kuan Liu, Jun Xiang Zhan, Wei Cheng Lin, Ching Che Kao, Chia Her Lin^*, Vítězslav Zima

^*此作品的通信作者

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

11 引文斯高帕斯（Scopus）

摘要

A new strontium metal-organic framework, [Sr₂(BTEC)(H ₂O)₄]2H₂O (1) (H₄BTEC = benzene-1,2,4,5-tetracarboxylic acid), has been successfully synthesized by mixing the starting reagents. The single-crystal structure analysis showed that compound 1 displayed three-dimensional structures containing inorganic motifs with two-dimensional layers pillar-connected through organic linkers and forming water-coordinated neutral framework. Further studies revealed that compound 1 was insoluble in water and that it emitted strong luminescence at approximately 437 nm after dehydration.

原文	英語
頁（從 - 到）	1602-1605
頁數	4
期刊	Inorganic Chemistry Communication
卷	14
發行號	10
DOIs	https://doi.org/10.1016/j.inoche.2011.06.017
出版狀態	已發佈 - 2011 10月
對外發佈	是

ASJC Scopus subject areas

物理與理論化學
無機化學
材料化學

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10.1016/j.inoche.2011.06.017

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@article{12478d6b39f74fb6a83ba4fbb0152410,

title = "Assembly of a water-insoluble strontium metal-organic framework with luminescent properties",

abstract = "A new strontium metal-organic framework, [Sr2(BTEC)(H 2O)4]2H2O (1) (H4BTEC = benzene-1,2,4,5-tetracarboxylic acid), has been successfully synthesized by mixing the starting reagents. The single-crystal structure analysis showed that compound 1 displayed three-dimensional structures containing inorganic motifs with two-dimensional layers pillar-connected through organic linkers and forming water-coordinated neutral framework. Further studies revealed that compound 1 was insoluble in water and that it emitted strong luminescence at approximately 437 nm after dehydration.",

keywords = "Luminescent, Metal-organic framework, Strontium complex, Water-insoluble",

author = "Lo, {Sheng Han} and Liu, {Hsin Kuan} and Zhan, {Jun Xiang} and Lin, {Wei Cheng} and Kao, {Ching Che} and Lin, {Chia Her} and V{\'i}t{\v e}zslav Zima",

note = "Funding Information: We gratefully acknowledge financial support from the National Science Council, Taiwan ( NSC99-2113-M-033-005-MY2 ). V. Z. thanks to the Czech Science Foundation (Project no. 203/08/0208 ) for the financial support. ",

year = "2011",

month = oct,

doi = "10.1016/j.inoche.2011.06.017",

language = "English",

volume = "14",

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journal = "Inorganic Chemistry Communication",

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AU - Lo, Sheng Han

AU - Liu, Hsin Kuan

AU - Zhan, Jun Xiang

AU - Lin, Wei Cheng

AU - Kao, Ching Che

AU - Lin, Chia Her

AU - Zima, Vítězslav

N1 - Funding Information: We gratefully acknowledge financial support from the National Science Council, Taiwan ( NSC99-2113-M-033-005-MY2 ). V. Z. thanks to the Czech Science Foundation (Project no. 203/08/0208 ) for the financial support.

PY - 2011/10

Y1 - 2011/10

N2 - A new strontium metal-organic framework, [Sr2(BTEC)(H 2O)4]2H2O (1) (H4BTEC = benzene-1,2,4,5-tetracarboxylic acid), has been successfully synthesized by mixing the starting reagents. The single-crystal structure analysis showed that compound 1 displayed three-dimensional structures containing inorganic motifs with two-dimensional layers pillar-connected through organic linkers and forming water-coordinated neutral framework. Further studies revealed that compound 1 was insoluble in water and that it emitted strong luminescence at approximately 437 nm after dehydration.

AB - A new strontium metal-organic framework, [Sr2(BTEC)(H 2O)4]2H2O (1) (H4BTEC = benzene-1,2,4,5-tetracarboxylic acid), has been successfully synthesized by mixing the starting reagents. The single-crystal structure analysis showed that compound 1 displayed three-dimensional structures containing inorganic motifs with two-dimensional layers pillar-connected through organic linkers and forming water-coordinated neutral framework. Further studies revealed that compound 1 was insoluble in water and that it emitted strong luminescence at approximately 437 nm after dehydration.

KW - Luminescent

KW - Metal-organic framework

KW - Strontium complex

KW - Water-insoluble

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DO - 10.1016/j.inoche.2011.06.017

M3 - Article

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SN - 1387-7003

VL - 14

SP - 1602

EP - 1605

JO - Inorganic Chemistry Communication

JF - Inorganic Chemistry Communication

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Assembly of a water-insoluble strontium metal-organic framework with luminescent properties

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