Anomalous Pr Ordering and Structural Analysis for Oxygenated Tetragonal 1212 Compound Pr1.5Ba1.5Cu3O7.2

H. C. Ku*, H. M. Luo, Y. P. Chi, B. N. Lin, Y. Y. Hsu, T. J. Lee, J. B. Shi, H. C.I. Kao

*此作品的通信作者

研究成果: 雜誌貢獻期刊論文同行評審

3 引文 斯高帕斯(Scopus)

摘要

Magnetic measurement and powder X-ray Rietveld analysis are performed on oxygenated Pri1.5Ba1.5Cu3O7.2 cuprate. This tetragonal compound with lattice parameters a = 0.38916 nm and c = 1.16177 nm is found to form the TlBa2CaCu2O7 1212-type structure when written as Cu[Ba1.5Pr0.5]PrCu2O7.2. Low temperature magnetic data indicate that anomalous Pr order temperature TN(Pr) decreases from 18 K for orthorhombic PrBa2Cu3O6.9 to 10.5 K for Pr1.5Ba1.5Cu3O7.2. The increasing Pr-O bond length with decreasing TN indicates that Pr ordering is closely correlated with the wave function overlap between Pr-4f orbital and O-2pπ orbital in the CuO2 bi-layers.

原文英語
頁(從 - 到)885-889
頁數5
期刊Journal of Low Temperature Physics
117
發行號3-4
DOIs
出版狀態已發佈 - 1999
對外發佈

ASJC Scopus subject areas

  • 原子與分子物理與光學
  • 材料科學(全部)
  • 凝聚態物理學

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