An unprecedented hydride abstraction from tricarbonyl[ethyl exo-3-[1-4- η-1,3-cyclohexadien-5-yl]propionate]iron complex

Ming Chang P. Yeh; Bi Ai Sheu; Ming Yuan Wang

doi:10.1016/S0040-4039(98)01229-5

An unprecedented hydride abstraction from tricarbonyl[ethyl exo-3-[1-4- η-1,3-cyclohexadien-5-yl]propionate]iron complex

Ming Chang P. Yeh^*, Bi Ai Sheu, Ming Yuan Wang

^*此作品的通信作者

化學系

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

2 引文斯高帕斯（Scopus）

摘要

The addition of triphenylcarbenium hexafluorophosphate to the title complex gives tricarbonyl(η⁵-cyclohexadienylium)iron hexafluorophosphate with a side chain at the C-1 position of the ring. Intramolecular cyclization of the cation using sodium- or calcium- hydride generates a heterospiro[4,5]decane derivative.

原文	英語
頁（從 - 到）	5987-5990
頁數	4
期刊	Tetrahedron Letters
卷	39
發行號	33
DOIs	https://doi.org/10.1016/S0040-4039(98)01229-5
出版狀態	已發佈 - 1998 8月 13

ASJC Scopus subject areas

生物化學
藥物發現
有機化學

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10.1016/S0040-4039(98)01229-5

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abstract = "The addition of triphenylcarbenium hexafluorophosphate to the title complex gives tricarbonyl(η5-cyclohexadienylium)iron hexafluorophosphate with a side chain at the C-1 position of the ring. Intramolecular cyclization of the cation using sodium- or calcium- hydride generates a heterospiro[4,5]decane derivative.",

author = "Yeh, {Ming Chang P.} and Sheu, {Bi Ai} and Wang, {Ming Yuan}",

year = "1998",

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AU - Yeh, Ming Chang P.

AU - Sheu, Bi Ai

AU - Wang, Ming Yuan

PY - 1998/8/13

Y1 - 1998/8/13

N2 - The addition of triphenylcarbenium hexafluorophosphate to the title complex gives tricarbonyl(η5-cyclohexadienylium)iron hexafluorophosphate with a side chain at the C-1 position of the ring. Intramolecular cyclization of the cation using sodium- or calcium- hydride generates a heterospiro[4,5]decane derivative.

AB - The addition of triphenylcarbenium hexafluorophosphate to the title complex gives tricarbonyl(η5-cyclohexadienylium)iron hexafluorophosphate with a side chain at the C-1 position of the ring. Intramolecular cyclization of the cation using sodium- or calcium- hydride generates a heterospiro[4,5]decane derivative.

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JO - Tetrahedron Letters

JF - Tetrahedron Letters

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ER -

An unprecedented hydride abstraction from tricarbonyl[ethyl exo-3-[1-4- η-1,3-cyclohexadien-5-yl]propionate]iron complex

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