An efficient synthesis of trisubstituted oxazoles via chemoselective o-acylations and intramolecular wittig reactions

Yi Ling Tsai; Yu Shiou Fan; Chia Jui Lee; Chan Hui Huang; Utpal Das; Wenwei Lin

doi:10.1039/c3cc45862h

An efficient synthesis of trisubstituted oxazoles via chemoselective o-acylations and intramolecular wittig reactions

Yi Ling Tsai
, Yu Shiou Fan
, Chia Jui Lee
, Chan Hui Huang
, Utpal Das
, Wenwei Lin^*

^*此作品的通信作者

化學系

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

2 引文斯高帕斯（Scopus）

摘要

Preparation of new types of trisubstituted oxazoles is realized via chemoselective O-acylations and intramolecular Wittig reactions with ester functionalities using in situ formed phosphorus ylides as key intermediates. A plausible reaction mechanism for this undiscovered chemistry is also proposed based on the existence of expected and rearranged isomeric oxazoles.

原文	英語
頁（從 - 到）	10308-10310
頁數	3
期刊	Chemical Communications
卷	49
發行號	87
DOIs	https://doi.org/10.1039/c3cc45862h
出版狀態	已發佈 - 2013 10月 8

ASJC Scopus subject areas

電子、光磁材料
催化
陶瓷和複合材料
一般化學
表面、塗料和薄膜
金屬和合金
材料化學

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10.1039/c3cc45862h

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title = "An efficient synthesis of trisubstituted oxazoles via chemoselective o-acylations and intramolecular wittig reactions",

abstract = "Preparation of new types of trisubstituted oxazoles is realized via chemoselective O-acylations and intramolecular Wittig reactions with ester functionalities using in situ formed phosphorus ylides as key intermediates. A plausible reaction mechanism for this undiscovered chemistry is also proposed based on the existence of expected and rearranged isomeric oxazoles.",

author = "Tsai, \{Yi Ling\} and Fan, \{Yu Shiou\} and Lee, \{Chia Jui\} and Huang, \{Chan Hui\} and Utpal Das and Wenwei Lin",

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T1 - An efficient synthesis of trisubstituted oxazoles via chemoselective o-acylations and intramolecular wittig reactions

AU - Tsai, Yi Ling

AU - Fan, Yu Shiou

AU - Lee, Chia Jui

AU - Huang, Chan Hui

AU - Das, Utpal

AU - Lin, Wenwei

PY - 2013/10/8

Y1 - 2013/10/8

N2 - Preparation of new types of trisubstituted oxazoles is realized via chemoselective O-acylations and intramolecular Wittig reactions with ester functionalities using in situ formed phosphorus ylides as key intermediates. A plausible reaction mechanism for this undiscovered chemistry is also proposed based on the existence of expected and rearranged isomeric oxazoles.

AB - Preparation of new types of trisubstituted oxazoles is realized via chemoselective O-acylations and intramolecular Wittig reactions with ester functionalities using in situ formed phosphorus ylides as key intermediates. A plausible reaction mechanism for this undiscovered chemistry is also proposed based on the existence of expected and rearranged isomeric oxazoles.

UR - https://www.scopus.com/pages/publications/85033243791

UR - https://www.scopus.com/pages/publications/85033243791#tab=citedBy

U2 - 10.1039/c3cc45862h

DO - 10.1039/c3cc45862h

M3 - Article

AN - SCOPUS:85033243791

SN - 1359-7345

VL - 49

SP - 10308

EP - 10310

JO - Chemical Communications

JF - Chemical Communications

IS - 87

ER -

An efficient synthesis of trisubstituted oxazoles via chemoselective o-acylations and intramolecular wittig reactions

摘要

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