An efficient synthesis of trisubstituted oxazoles via chemoselective o-acylations and intramolecular wittig reactions

Yi Ling Tsai; Yu Shiou Fan; Chia Jui Lee; Chan Hui Huang; Utpal Das; Wenwei Lin

doi:10.1039/c3cc45883k

An efficient synthesis of trisubstituted oxazoles via chemoselective o-acylations and intramolecular wittig reactions

Yi Ling Tsai
, Yu Shiou Fan
, Chia Jui Lee
, Chan Hui Huang
, Utpal Das
, Wenwei Lin^*

^*此作品的通信作者

化學系

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

46 引文斯高帕斯（Scopus）

摘要

Preparation of new types of trisubstituted oxazoles is realized via chemoselective O-acylations and intramolecular Wittig reactions with ester functionalities using in situ formed phosphorus ylides as key intermediates. A plausible reaction mechanism for this undiscovered chemistry is also proposed based on the existence of expected and rearranged isomeric oxazoles.

原文	英語
頁（從 - 到）	10266-10268
頁數	3
期刊	Chemical Communications
卷	49
發行號	87
DOIs	https://doi.org/10.1039/c3cc45883k
出版狀態	已發佈 - 2013 10月 8

ASJC Scopus subject areas

電子、光磁材料
催化
陶瓷和複合材料
一般化學
表面、塗料和薄膜
金屬和合金
材料化學

存取文件

10.1039/c3cc45883k

其它文件與鏈接

CCDC 940037: Experimental Crystal Structure Determination
Tsai, Y.-L. (Creator), Fan, Y.-S. (Creator), Lee, C.-J. (Creator), Huang, C.-H. (Creator), Das, U. (Creator) & Lin, W. (Creator), Unknown Publisher, 2013
DOI: 10.5517/cc10k5sj, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc10k5sj&sid=DataCite
資料集: Dataset
CCDC 940036: Experimental Crystal Structure Determination
Tsai, Y.-L. (Creator), Fan, Y.-S. (Creator), Lee, C.-J. (Creator), Huang, C.-H. (Creator), Das, U. (Creator) & Lin, W. (Creator), Unknown Publisher, 2013
DOI: 10.5517/cc10k5rh, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc10k5rh&sid=DataCite
資料集: Dataset
CCDC 940042: Experimental Crystal Structure Determination
Tsai, Y.-L. (Creator), Fan, Y.-S. (Creator), Lee, C.-J. (Creator), Huang, C.-H. (Creator), Das, U. (Creator) & Lin, W. (Creator), Unknown Publisher, 2013
DOI: 10.5517/cc10k5yp, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc10k5yp&sid=DataCite
資料集: Dataset

引用此

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title = "An efficient synthesis of trisubstituted oxazoles via chemoselective o-acylations and intramolecular wittig reactions",

abstract = "Preparation of new types of trisubstituted oxazoles is realized via chemoselective O-acylations and intramolecular Wittig reactions with ester functionalities using in situ formed phosphorus ylides as key intermediates. A plausible reaction mechanism for this undiscovered chemistry is also proposed based on the existence of expected and rearranged isomeric oxazoles.",

author = "Tsai, \{Yi Ling\} and Fan, \{Yu Shiou\} and Lee, \{Chia Jui\} and Huang, \{Chan Hui\} and Utpal Das and Wenwei Lin",

year = "2013",

month = oct,

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doi = "10.1039/c3cc45883k",

language = "English",

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journal = "Chemical Communications",

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T1 - An efficient synthesis of trisubstituted oxazoles via chemoselective o-acylations and intramolecular wittig reactions

AU - Tsai, Yi Ling

AU - Fan, Yu Shiou

AU - Lee, Chia Jui

AU - Huang, Chan Hui

AU - Das, Utpal

AU - Lin, Wenwei

PY - 2013/10/8

Y1 - 2013/10/8

N2 - Preparation of new types of trisubstituted oxazoles is realized via chemoselective O-acylations and intramolecular Wittig reactions with ester functionalities using in situ formed phosphorus ylides as key intermediates. A plausible reaction mechanism for this undiscovered chemistry is also proposed based on the existence of expected and rearranged isomeric oxazoles.

AB - Preparation of new types of trisubstituted oxazoles is realized via chemoselective O-acylations and intramolecular Wittig reactions with ester functionalities using in situ formed phosphorus ylides as key intermediates. A plausible reaction mechanism for this undiscovered chemistry is also proposed based on the existence of expected and rearranged isomeric oxazoles.

UR - https://www.scopus.com/pages/publications/84885395392

UR - https://www.scopus.com/pages/publications/84885395392#tab=citedBy

U2 - 10.1039/c3cc45883k

DO - 10.1039/c3cc45883k

M3 - Article

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AN - SCOPUS:84885395392

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VL - 49

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JO - Chemical Communications

JF - Chemical Communications

IS - 87

ER -

An efficient synthesis of trisubstituted oxazoles via chemoselective o-acylations and intramolecular wittig reactions

摘要

ASJC Scopus subject areas

存取文件

其它文件與鏈接

指紋

資料集

CCDC 940037: Experimental Crystal Structure Determination

CCDC 940036: Experimental Crystal Structure Determination

CCDC 940042: Experimental Crystal Structure Determination

引用此