摘要
Preparation of new types of trisubstituted oxazoles is realized via chemoselective O-acylations and intramolecular Wittig reactions with ester functionalities using in situ formed phosphorus ylides as key intermediates. A plausible reaction mechanism for this undiscovered chemistry is also proposed based on the existence of expected and rearranged isomeric oxazoles.
| 原文 | 英語 |
|---|---|
| 頁（從 - 到） | 10266-10268 |
| 頁數 | 3 |
| 期刊 | Chemical Communications |
| 卷 | 49 |
| 發行號 | 87 |
| DOIs | |
| 出版狀態 | 已發佈 - 2013 10月 8 |
ASJC Scopus subject areas
- 電子、光磁材料
- 催化
- 陶瓷和複合材料
- 一般化學
- 表面、塗料和薄膜
- 金屬和合金
- 材料化學
指紋
深入研究「An efficient synthesis of trisubstituted oxazoles via chemoselective o-acylations and intramolecular wittig reactions」主題。共同形成了獨特的指紋。資料集
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CCDC 940038: Experimental Crystal Structure Determination
Tsai, Y.-L. (Creator), Fan, Y.-S. (Creator), Lee, C.-J. (Creator), Huang, C.-H. (Creator), Das, U. (Creator) & Lin, W. (Creator), Unknown Publisher, 2013
DOI: 10.5517/cc10k5tk, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc10k5tk&sid=DataCite
資料集: Dataset
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CCDC 940037: Experimental Crystal Structure Determination
Tsai, Y.-L. (Creator), Fan, Y.-S. (Creator), Lee, C.-J. (Creator), Huang, C.-H. (Creator), Das, U. (Creator) & Lin, W. (Creator), Unknown Publisher, 2013
DOI: 10.5517/cc10k5sj, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc10k5sj&sid=DataCite
資料集: Dataset
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CCDC 940035: Experimental Crystal Structure Determination
Tsai, Y.-L. (Creator), Fan, Y.-S. (Creator), Lee, C.-J. (Creator), Huang, C.-H. (Creator), Das, U. (Creator) & Lin, W. (Creator), Unknown Publisher, 2013
DOI: 10.5517/cc10k5qg, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc10k5qg&sid=DataCite
資料集: Dataset