An efficient of Grignard-type procedure for the preparation of gem-diallylated compound

Kao Hsien Shen, Chun Wei Kuo, Ching Fa Yao*

*此作品的通信作者

研究成果: 雜誌貢獻期刊論文同行評審

11 引文 斯高帕斯(Scopus)

摘要

An efficient and a new procedure for the conversion of various carboxylic acid derivatives into the corresponding gem-diallylated compound under mild reaction condition has been developed. The triallylaluminum mediated Grignard-type addition of carboxylic acid derivative was utilized as a key operation to affect the transformation. The procedure is operationally simple, giving good to excellent product yields for a broad range of substrates. The chemoselectivity and regioselectivity of triallylaluminum were also demonstrated.

原文英語
頁(從 - 到)6348-6351
頁數4
期刊Tetrahedron Letters
48
發行號36
DOIs
出版狀態已發佈 - 2007 九月 3

ASJC Scopus subject areas

  • 生物化學
  • 藥物發現
  • 有機化學

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