Ambiphilicity of a mononuclear cobalt(iii) superoxo complex

Ting Yi Chen; Po Hsun Ho; Can Jerome Spyra; Franc Meyer; Eckhard Bill; Shengfa Ye; Way Zen Lee

doi:10.1039/d0cc05337f

Ambiphilicity of a mononuclear cobalt(iii) superoxo complex

Ting Yi Chen, Po Hsun Ho, Can Jerome Spyra, Franc Meyer^*, Eckhard Bill, Shengfa Ye^*, Way Zen Lee^*

^*此作品的通信作者

化學系

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

5 引文斯高帕斯（Scopus）

摘要

Addition of HOTf to a mixture of CoIII(BDPP)(O2) (1, H2BDPP = 2,6-bis((2-(S)-diphenylhydroxylmethyl-1-pyrrolidinyl)methyl)pyridine) and Cp∗2Fe produced H2O2 in high yield implying formation of CoIII(BDPP)(OOH) (3), and reaction of Sc(OTf)3 with the same mixture gave a peroxo-bridged CoIII/ScIII5. These findings demonstrate the ambiphilic property of CoIII-superoxo 1.

原文	英語
頁（從 - 到）	14821-14824
頁數	4
期刊	Chemical Communications
卷	56
發行號	94
DOIs	https://doi.org/10.1039/d0cc05337f
出版狀態	已發佈 - 2020 12月 7

ASJC Scopus subject areas

催化
電子、光磁材料
陶瓷和複合材料
一般化學
表面、塗料和薄膜
金屬和合金
材料化學

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title = "Ambiphilicity of a mononuclear cobalt(iii) superoxo complex",

abstract = "Addition of HOTf to a mixture of CoIII(BDPP)(O2) (1, H2BDPP = 2,6-bis((2-(S)-diphenylhydroxylmethyl-1-pyrrolidinyl)methyl)pyridine) and Cp∗2Fe produced H2O2 in high yield implying formation of CoIII(BDPP)(OOH) (3), and reaction of Sc(OTf)3 with the same mixture gave a peroxo-bridged CoIII/ScIII5. These findings demonstrate the ambiphilic property of CoIII-superoxo 1.",

author = "Chen, {Ting Yi} and Ho, {Po Hsun} and Spyra, {Can Jerome} and Franc Meyer and Eckhard Bill and Shengfa Ye and Lee, {Way Zen}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

year = "2020",

month = dec,

day = "7",

doi = "10.1039/d0cc05337f",

language = "English",

volume = "56",

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T1 - Ambiphilicity of a mononuclear cobalt(iii) superoxo complex

AU - Chen, Ting Yi

AU - Ho, Po Hsun

AU - Spyra, Can Jerome

AU - Meyer, Franc

AU - Bill, Eckhard

AU - Ye, Shengfa

AU - Lee, Way Zen

PY - 2020/12/7

Y1 - 2020/12/7

N2 - Addition of HOTf to a mixture of CoIII(BDPP)(O2) (1, H2BDPP = 2,6-bis((2-(S)-diphenylhydroxylmethyl-1-pyrrolidinyl)methyl)pyridine) and Cp∗2Fe produced H2O2 in high yield implying formation of CoIII(BDPP)(OOH) (3), and reaction of Sc(OTf)3 with the same mixture gave a peroxo-bridged CoIII/ScIII5. These findings demonstrate the ambiphilic property of CoIII-superoxo 1.

AB - Addition of HOTf to a mixture of CoIII(BDPP)(O2) (1, H2BDPP = 2,6-bis((2-(S)-diphenylhydroxylmethyl-1-pyrrolidinyl)methyl)pyridine) and Cp∗2Fe produced H2O2 in high yield implying formation of CoIII(BDPP)(OOH) (3), and reaction of Sc(OTf)3 with the same mixture gave a peroxo-bridged CoIII/ScIII5. These findings demonstrate the ambiphilic property of CoIII-superoxo 1.

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DO - 10.1039/d0cc05337f

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EP - 14824

JO - Chemical Communications

JF - Chemical Communications

IS - 94

ER -

Ambiphilicity of a mononuclear cobalt(iii) superoxo complex

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