Ambiphilicity of a mononuclear cobalt(iii) superoxo complex

Ting Yi Chen, Po Hsun Ho, Can Jerome Spyra, Franc Meyer, Eckhard Bill, Shengfa Ye, Way Zen Lee*

*此作品的通信作者

研究成果: 雜誌貢獻期刊論文同行評審

摘要

Addition of HOTf to a mixture of CoIII(BDPP)(O2) (1, H2BDPP = 2,6-bis((2-(S)-diphenylhydroxylmethyl-1-pyrrolidinyl)methyl)pyridine) and Cp∗2Fe produced H2O2 in high yield implying formation of CoIII(BDPP)(OOH) (3), and reaction of Sc(OTf)3 with the same mixture gave a peroxo-bridged CoIII/ScIII5. These findings demonstrate the ambiphilic property of CoIII-superoxo 1. This journal is

原文英語
頁(從 - 到)14821-14824
頁數4
期刊Chemical Communications
56
發行號94
DOIs
出版狀態已發佈 - 2020 十二月 7

ASJC Scopus subject areas

  • 催化
  • 電子、光磁材料
  • 陶瓷和複合材料
  • 化學 (全部)
  • 表面、塗料和薄膜
  • 金屬和合金
  • 材料化學

指紋

深入研究「Ambiphilicity of a mononuclear cobalt(iii) superoxo complex」主題。共同形成了獨特的指紋。

引用此