Alkylation of the (η4-cyclohexa-1,3-diene) (η5-cyclopentadienyl)(dicarbonyl)-molybdenum hexafluorophosphate with the highly functionalized zinc-copper reagents RCu(CN)Znl

Ming Chang P. Yeh; Chung Jy Tsou; Chong Nan Chuang; Hwei Chi Lin

doi:10.1039/C39920000890

Alkylation of the (η⁴-cyclohexa-1,3-diene) (η⁵-cyclopentadienyl)(dicarbonyl)-molybdenum hexafluorophosphate with the highly functionalized zinc-copper reagents RCu(CN)Znl

Ming Chang P. Yeh^*, Chung Jy Tsou, Chong Nan Chuang, Hwei Chi Lin

^*此作品的通信作者

化學系

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

15 引文斯高帕斯（Scopus）

摘要

The addition of a variety of the highly functionalized zinc-copper reagents RCu(CN)Znl to the title cation at the terminus of the coordinated diene ligand gives [Mo(π-allyl)(CO)₂(Cp)] (Cp = cyclopentadienyl) complexes with the functionalized side-chain at the C-4 position of the ring: intramolecular cyclisation of the (π-allyl)molybdenum complex 4 containing a pendant propanoic acid unit generates the δ-lactone derivative 6.

原文	英語
頁（從 - 到）	890-891
頁數	2
期刊	Journal of the Chemical Society, Chemical Communications
發行號	12
DOIs	https://doi.org/10.1039/C39920000890
出版狀態	已發佈 - 1992

ASJC Scopus subject areas

分子醫學

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10.1039/C39920000890

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Alkylation of the (η⁴-cyclohexa-1,3-diene) (η⁵-cyclopentadienyl)(dicarbonyl)-molybdenum hexafluorophosphate with the highly functionalized zinc-copper reagents RCu(CN)Znl. / Yeh, Ming Chang P.; Tsou, Chung Jy; Chuang, Chong Nan; Lin, Hwei Chi.

於: Journal of the Chemical Society, Chemical Communications, 編號 12, 1992, p. 890-891.

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

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title = "Alkylation of the (η4-cyclohexa-1,3-diene) (η5-cyclopentadienyl)(dicarbonyl)-molybdenum hexafluorophosphate with the highly functionalized zinc-copper reagents RCu(CN)Znl",

abstract = "The addition of a variety of the highly functionalized zinc-copper reagents RCu(CN)Znl to the title cation at the terminus of the coordinated diene ligand gives [Mo(π-allyl)(CO)2(Cp)] (Cp = cyclopentadienyl) complexes with the functionalized side-chain at the C-4 position of the ring: intramolecular cyclisation of the (π-allyl)molybdenum complex 4 containing a pendant propanoic acid unit generates the δ-lactone derivative 6.",

author = "Yeh, {Ming Chang P.} and Tsou, {Chung Jy} and Chuang, {Chong Nan} and Lin, {Hwei Chi}",

year = "1992",

doi = "10.1039/C39920000890",

language = "English",

pages = "890--891",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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T1 - Alkylation of the (η4-cyclohexa-1,3-diene) (η5-cyclopentadienyl)(dicarbonyl)-molybdenum hexafluorophosphate with the highly functionalized zinc-copper reagents RCu(CN)Znl

AU - Yeh, Ming Chang P.

AU - Tsou, Chung Jy

AU - Chuang, Chong Nan

AU - Lin, Hwei Chi

PY - 1992

Y1 - 1992

N2 - The addition of a variety of the highly functionalized zinc-copper reagents RCu(CN)Znl to the title cation at the terminus of the coordinated diene ligand gives [Mo(π-allyl)(CO)2(Cp)] (Cp = cyclopentadienyl) complexes with the functionalized side-chain at the C-4 position of the ring: intramolecular cyclisation of the (π-allyl)molybdenum complex 4 containing a pendant propanoic acid unit generates the δ-lactone derivative 6.

AB - The addition of a variety of the highly functionalized zinc-copper reagents RCu(CN)Znl to the title cation at the terminus of the coordinated diene ligand gives [Mo(π-allyl)(CO)2(Cp)] (Cp = cyclopentadienyl) complexes with the functionalized side-chain at the C-4 position of the ring: intramolecular cyclisation of the (π-allyl)molybdenum complex 4 containing a pendant propanoic acid unit generates the δ-lactone derivative 6.

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UR - http://www.scopus.com/inward/citedby.url?scp=37049080628&partnerID=8YFLogxK

U2 - 10.1039/C39920000890

DO - 10.1039/C39920000890

M3 - Article

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SP - 890

EP - 891

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 12

ER -

Alkylation of the (η4-cyclohexa-1,3-diene) (η5-cyclopentadienyl)(dicarbonyl)-molybdenum hexafluorophosphate with the highly functionalized zinc-copper reagents RCu(CN)Znl

摘要

ASJC Scopus subject areas

存取文件

其它文件與鏈接

指紋

引用此

Alkylation of the (η⁴-cyclohexa-1,3-diene) (η⁵-cyclopentadienyl)(dicarbonyl)-molybdenum hexafluorophosphate with the highly functionalized zinc-copper reagents RCu(CN)Znl