Addition reactions of lithiodimethylphenylsilane to (η4-1,3-diene)-Fe(CO)3 and (η6-arene)Cr(CO)3 complexes

Ming Chang P. Yeh; Peng Yu Sheu; Jin Xuan Ho; Yi Lin Chiang; Dai Yu Chiu; U. Narasimha Rao

doi:10.1016/S0022-328X(03)00219-5

Addition reactions of lithiodimethylphenylsilane to (η⁴-1,3-diene)-Fe(CO)₃ and (η⁶-arene)Cr(CO)₃ complexes

Ming Chang P. Yeh^*, Peng Yu Sheu, Jin Xuan Ho, Yi Lin Chiang, Dai Yu Chiu, U. Narasimha Rao

^*此作品的通信作者

化學系

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

4 引文斯高帕斯（Scopus）

摘要

Treatments of (η⁴-cyclohexa-1,3-diene)Fe(CO)₃ complex with 1.2 equivalents of PhMe₂SiLi, followed by quenching the reactive intermediate with CF₃COOH generated 1-dimethyl(phenyl)silylcyclohex-1-ene and with 2-(phenylsulfonyl)-3-phenyloxaziridine produced [η⁴-2-dimethyl(phenyl)silylcyclohexa-1,3-diene]Fe (CO)₃ complex as the major product. Additions of the silyl anion to (η⁶-arene)Cr(CO)₃ and (η⁶-cyclohepta-1,3,5-triene)Cr(CO)₃ complexes produce dienylsilanes after acid quenching.

原文	英語
頁（從 - 到）	13-20
頁數	8
期刊	Journal of Organometallic Chemistry
卷	675
發行號	1-2
DOIs	https://doi.org/10.1016/S0022-328X(03)00219-5
出版狀態	已發佈 - 2003 5月 30

ASJC Scopus subject areas

生物化學
物理與理論化學
有機化學
無機化學
材料化學

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10.1016/S0022-328X(03)00219-5

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@article{3369373c9b6c484ab7f44bb0b1d07484,

title = "Addition reactions of lithiodimethylphenylsilane to (η4-1,3-diene)-Fe(CO)3 and (η6-arene)Cr(CO)3 complexes",

abstract = "Treatments of (η4-cyclohexa-1,3-diene)Fe(CO)3 complex with 1.2 equivalents of PhMe2SiLi, followed by quenching the reactive intermediate with CF3COOH generated 1-dimethyl(phenyl)silylcyclohex-1-ene and with 2-(phenylsulfonyl)-3-phenyloxaziridine produced [η4-2-dimethyl(phenyl)silylcyclohexa-1,3-diene]Fe (CO)3 complex as the major product. Additions of the silyl anion to (η6-arene)Cr(CO)3 and (η6-cyclohepta-1,3,5-triene)Cr(CO)3 complexes produce dienylsilanes after acid quenching.",

keywords = "Arene, Chromium, Cyclohexadiene, Iron, Silane",

author = "Yeh, {Ming Chang P.} and Sheu, {Peng Yu} and Ho, {Jin Xuan} and Chiang, {Yi Lin} and Chiu, {Dai Yu} and {Narasimha Rao}, U.",

note = "Funding Information: This work was supported by grants from National Taiwan Normal University (ORD91-1) and the National Science Council (NSC 90-2113-M-003-008). ",

year = "2003",

month = may,

day = "30",

doi = "10.1016/S0022-328X(03)00219-5",

language = "English",

volume = "675",

pages = "13--20",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier",

number = "1-2",

}

TY - JOUR

T1 - Addition reactions of lithiodimethylphenylsilane to (η4-1,3-diene)-Fe(CO)3 and (η6-arene)Cr(CO)3 complexes

AU - Yeh, Ming Chang P.

AU - Sheu, Peng Yu

AU - Ho, Jin Xuan

AU - Chiang, Yi Lin

AU - Chiu, Dai Yu

AU - Narasimha Rao, U.

N1 - Funding Information: This work was supported by grants from National Taiwan Normal University (ORD91-1) and the National Science Council (NSC 90-2113-M-003-008).

PY - 2003/5/30

Y1 - 2003/5/30

N2 - Treatments of (η4-cyclohexa-1,3-diene)Fe(CO)3 complex with 1.2 equivalents of PhMe2SiLi, followed by quenching the reactive intermediate with CF3COOH generated 1-dimethyl(phenyl)silylcyclohex-1-ene and with 2-(phenylsulfonyl)-3-phenyloxaziridine produced [η4-2-dimethyl(phenyl)silylcyclohexa-1,3-diene]Fe (CO)3 complex as the major product. Additions of the silyl anion to (η6-arene)Cr(CO)3 and (η6-cyclohepta-1,3,5-triene)Cr(CO)3 complexes produce dienylsilanes after acid quenching.

AB - Treatments of (η4-cyclohexa-1,3-diene)Fe(CO)3 complex with 1.2 equivalents of PhMe2SiLi, followed by quenching the reactive intermediate with CF3COOH generated 1-dimethyl(phenyl)silylcyclohex-1-ene and with 2-(phenylsulfonyl)-3-phenyloxaziridine produced [η4-2-dimethyl(phenyl)silylcyclohexa-1,3-diene]Fe (CO)3 complex as the major product. Additions of the silyl anion to (η6-arene)Cr(CO)3 and (η6-cyclohepta-1,3,5-triene)Cr(CO)3 complexes produce dienylsilanes after acid quenching.

KW - Arene

KW - Chromium

KW - Cyclohexadiene

KW - Iron

KW - Silane

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U2 - 10.1016/S0022-328X(03)00219-5

DO - 10.1016/S0022-328X(03)00219-5

M3 - Article

AN - SCOPUS:0037612184

VL - 675

SP - 13

EP - 20

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

SN - 0022-328X

IS - 1-2

ER -

Addition reactions of lithiodimethylphenylsilane to (η4-1,3-diene)-Fe(CO)3 and (η6-arene)Cr(CO)3 complexes

摘要

ASJC Scopus subject areas

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Addition reactions of lithiodimethylphenylsilane to (η⁴-1,3-diene)-Fe(CO)₃ and (η⁶-arene)Cr(CO)₃ complexes