摘要
Treatments of (η4-cyclohexa-1,3-diene)Fe(CO)3 complex with 1.2 equivalents of PhMe2SiLi, followed by quenching the reactive intermediate with CF3COOH generated 1-dimethyl(phenyl)silylcyclohex-1-ene and with 2-(phenylsulfonyl)-3-phenyloxaziridine produced [η4-2-dimethyl(phenyl)silylcyclohexa-1,3-diene]Fe (CO)3 complex as the major product. Additions of the silyl anion to (η6-arene)Cr(CO)3 and (η6-cyclohepta-1,3,5-triene)Cr(CO)3 complexes produce dienylsilanes after acid quenching.
原文 | 英語 |
---|---|
頁(從 - 到) | 13-20 |
頁數 | 8 |
期刊 | Journal of Organometallic Chemistry |
卷 | 675 |
發行號 | 1-2 |
DOIs | |
出版狀態 | 已發佈 - 2003 5月 30 |
ASJC Scopus subject areas
- 生物化學
- 物理與理論化學
- 有機化學
- 無機化學
- 材料化學