A Water-Soluble Rhenium(I) Catalyst for the Regio- And Stereoselective C(sp2)-H Alkenylation of N-Pyridyl-/ N-Pyrimidylindole and the N-H Alkenylation of N-Pyrimidylaniline Derivatives with Ynamides

Sundaramoorthi Sarathkumar, Veerababurao Kavala, Ching Fa Yao*

*此作品的通信作者

研究成果: 雜誌貢獻期刊論文同行評審

1 引文 斯高帕斯(Scopus)

摘要

A water-soluble and low-valent rhenium(I) catalyst for the C2 alkenylation of N-pyridyl/N-pyrimidylindole derivatives with ynamides under mild conditions using water as the solvent has been described. The reaction of N-pyridyl/N-pyrimidyl indole with the ynamide afforded the C2-Z-selective alkenylation derivative as the sole product, and the reactions of N-pyrimidylanilines delivered the corresponding N-alkenylated product rather than the expected C-H alkenylation products in high yields under the same conditions.

原文英語
頁(從 - 到)1960-1965
頁數6
期刊Organic Letters
23
發行號6
DOIs
出版狀態已發佈 - 2021 三月 19

ASJC Scopus subject areas

  • 生物化學
  • 物理與理論化學
  • 有機化學

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