A titanium(iii) phosphite exhibits polymorph-distinct redox activity involving proton-coupled electron transfer

Ling I. Hung; Tsung Hsiu Hsieh; Jhao Yang Syu; Pei Lin Chen; Chia Her Lin; Sue Lein Wang

doi:10.1039/d1cc01190a

A titanium(iii) phosphite exhibits polymorph-distinct redox activity involving proton-coupled electron transfer

Ling I. Hung, Tsung Hsiu Hsieh, Jhao Yang Syu, Pei Lin Chen, Chia Her Lin, Sue Lein Wang^*

^*此作品的通信作者

化學系

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

1 引文斯高帕斯（Scopus）

摘要

A novel titanium(iii) phosphite with intriguing polymorphism and solid-state proton-coupled electron transfer (PCET) oxidation is presented. The polymorphs show structure-dependent PCET reactivity, interpretable by proton distribution in channels. Combined with subsequent photoreduction, the redox cycle initiated with Ti^IIIcan produce H₂and transform organics.

原文	英語
頁（從 - 到）	6542-6545
頁數	4
期刊	Chemical Communications
卷	57
發行號	53
DOIs	https://doi.org/10.1039/d1cc01190a
出版狀態	已發佈 - 2021 7月 7

ASJC Scopus subject areas

催化
電子、光磁材料
陶瓷和複合材料
一般化學
表面、塗料和薄膜
金屬和合金
材料化學

存取文件

10.1039/d1cc01190a

其它文件與鏈接

Link to publication in Scopus

CSD 2063409: Experimental Crystal Structure Determination
Hung, L. (Contributor), Hsieh, T. (Contributor), Syu, J. (Contributor), Chen, P. (Contributor), Lin, C. H. (Contributor) & Wang, S. (Contributor), FIZ Karlsruhe - Leibniz Institute for Information Infrastructure, 2021
DOI: 10.25505/fiz.icsd.cc2784l8, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.25505/fiz.icsd.cc2784l8&sid=DataCite
資料集: Dataset
CSD 2063412: Experimental Crystal Structure Determination
Hung, L. (Contributor), Hsieh, T. (Contributor), Syu, J. (Contributor), Chen, P. (Contributor), Lin, C. H. (Contributor) & Wang, S. (Contributor), FIZ Karlsruhe - Leibniz Institute for Information Infrastructure, 2021
DOI: 10.25505/fiz.icsd.cc2784pc, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.25505/fiz.icsd.cc2784pc&sid=DataCite
資料集: Dataset
CSD 2063411: Experimental Crystal Structure Determination
Hung, L. (Contributor), Hsieh, T. (Contributor), Syu, J. (Contributor), Chen, P. (Contributor), Lin, C. H. (Contributor) & Wang, S. (Contributor), FIZ Karlsruhe - Leibniz Institute for Information Infrastructure, 2021
DOI: 10.25505/fiz.icsd.cc2784nb, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.25505/fiz.icsd.cc2784nb&sid=DataCite
資料集: Dataset

引用此

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abstract = "A novel titanium(iii) phosphite with intriguing polymorphism and solid-state proton-coupled electron transfer (PCET) oxidation is presented. The polymorphs show structure-dependent PCET reactivity, interpretable by proton distribution in channels. Combined with subsequent photoreduction, the redox cycle initiated with TiIIIcan produce H2and transform organics.",

author = "Hung, {Ling I.} and Hsieh, {Tsung Hsiu} and Syu, {Jhao Yang} and Chen, {Pei Lin} and Lin, {Chia Her} and Wang, {Sue Lein}",

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year = "2021",

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AU - Hung, Ling I.

AU - Hsieh, Tsung Hsiu

AU - Syu, Jhao Yang

AU - Chen, Pei Lin

AU - Lin, Chia Her

AU - Wang, Sue Lein

PY - 2021/7/7

Y1 - 2021/7/7

N2 - A novel titanium(iii) phosphite with intriguing polymorphism and solid-state proton-coupled electron transfer (PCET) oxidation is presented. The polymorphs show structure-dependent PCET reactivity, interpretable by proton distribution in channels. Combined with subsequent photoreduction, the redox cycle initiated with TiIIIcan produce H2and transform organics.

AB - A novel titanium(iii) phosphite with intriguing polymorphism and solid-state proton-coupled electron transfer (PCET) oxidation is presented. The polymorphs show structure-dependent PCET reactivity, interpretable by proton distribution in channels. Combined with subsequent photoreduction, the redox cycle initiated with TiIIIcan produce H2and transform organics.

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EP - 6545

JO - Chemical Communications

JF - Chemical Communications

IS - 53

ER -

A titanium(iii) phosphite exhibits polymorph-distinct redox activity involving proton-coupled electron transfer

摘要

ASJC Scopus subject areas

存取文件

其它文件與鏈接

指紋

資料集

CSD 2063409: Experimental Crystal Structure Determination

CSD 2063412: Experimental Crystal Structure Determination

CSD 2063411: Experimental Crystal Structure Determination

引用此