A titanium(iii) phosphite exhibits polymorph-distinct redox activity involving proton-coupled electron transfer

Ling I. Hung, Tsung Hsiu Hsieh, Jhao Yang Syu, Pei Lin Chen, Chia Her Lin, Sue Lein Wang*

*此作品的通信作者

研究成果: 雜誌貢獻期刊論文同行評審

摘要

A novel titanium(iii) phosphite with intriguing polymorphism and solid-state proton-coupled electron transfer (PCET) oxidation is presented. The polymorphs show structure-dependent PCET reactivity, interpretable by proton distribution in channels. Combined with subsequent photoreduction, the redox cycle initiated with TiIIIcan produce H2and transform organics.

原文英語
頁(從 - 到)6542-6545
頁數4
期刊Chemical Communications
57
發行號53
DOIs
出版狀態已發佈 - 2021 七月 7

ASJC Scopus subject areas

  • 催化
  • 電子、光磁材料
  • 陶瓷和複合材料
  • 化學 (全部)
  • 表面、塗料和薄膜
  • 金屬和合金
  • 材料化學

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