A rigidity-modulated approach toward the construction of metallacycles from a flexible tetratopic ligand

Chuan Hung Chuang; Malaichamy Sathiyendiran; Yi Hsiu Tseng; Jing Yun Wu; Kung Chung Hsu; Chen Hsiung Hung; Yuh Sheng Wen; Kuang Lieh Lu

doi:10.1021/om9007604

A rigidity-modulated approach toward the construction of metallacycles from a flexible tetratopic ligand

Chuan Hung Chuang, Malaichamy Sathiyendiran, Yi Hsiu Tseng, Jing Yun Wu, Kung Chung Hsu, Chen Hsiung Hung, Yuh Sheng Wen, Kuang Lieh Lu^*

^*此作品的通信作者

化學系

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

11 引文斯高帕斯（Scopus）

摘要

Conformation control of a flexible tetratopic ligand by modulation of the length of the rigid bridging ligand is achieved during the self-assembly of metallacycles. The ability to control the conformation of the flexible ligand using an ancillary rigid ligand provides a new method for the preparation of novel metallacycles that contain both flexible and rigid modules with highly accurate prediction of the final structures.

原文	英語
頁（從 - 到）	283-285
頁數	3
期刊	Organometallics
卷	29
發行號	2
DOIs	https://doi.org/10.1021/om9007604
出版狀態	已發佈 - 2010 1月 25

ASJC Scopus subject areas

物理與理論化學
有機化學
無機化學

存取文件

10.1021/om9007604

其它文件與鏈接

CCDC 808391: Experimental Crystal Structure Determination
Chuang, C. (Creator), Sathiyendiran, M. (Contributor), Tseng, Y. (Creator), Wu, J. (Creator), Hsu, K. (Creator), Hung, C. (Creator), Wen, Y. (Creator) & Lu, K. (Creator), Unknown Publisher, 2011
DOI: 10.5517/ccw464b, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccw464b&sid=DataCite
資料集: Dataset
CCDC 701808: Experimental Crystal Structure Determination
Chuang, C. (Creator), Sathiyendiran, M. (Contributor), Tseng, Y. (Creator), Wu, J. (Creator), Hsu, K. (Creator), Hung, C. (Creator), Wen, Y. (Creator) & Lu, K. (Creator), Unknown Publisher, 2011
DOI: 10.5517/ccrk8zj, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccrk8zj&sid=DataCite
資料集: Dataset

引用此

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AU - Sathiyendiran, Malaichamy

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AU - Wu, Jing Yun

AU - Hsu, Kung Chung

AU - Hung, Chen Hsiung

AU - Wen, Yuh Sheng

AU - Lu, Kuang Lieh

PY - 2010/1/25

Y1 - 2010/1/25

N2 - Conformation control of a flexible tetratopic ligand by modulation of the length of the rigid bridging ligand is achieved during the self-assembly of metallacycles. The ability to control the conformation of the flexible ligand using an ancillary rigid ligand provides a new method for the preparation of novel metallacycles that contain both flexible and rigid modules with highly accurate prediction of the final structures.

AB - Conformation control of a flexible tetratopic ligand by modulation of the length of the rigid bridging ligand is achieved during the self-assembly of metallacycles. The ability to control the conformation of the flexible ligand using an ancillary rigid ligand provides a new method for the preparation of novel metallacycles that contain both flexible and rigid modules with highly accurate prediction of the final structures.

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A rigidity-modulated approach toward the construction of metallacycles from a flexible tetratopic ligand

摘要

ASJC Scopus subject areas

存取文件

其它文件與鏈接

指紋

資料集

CCDC 808391: Experimental Crystal Structure Determination

CCDC 701808: Experimental Crystal Structure Determination

引用此