A novel synthetic approach to medium ring lactones via dienetricarbonyliron complexes

Ming Liang Lai; Shun Chi Chang; Chung Chen Hwu; Ming Chang P. Yeh

doi:10.1016/0040-4039(96)01334-2

A novel synthetic approach to medium ring lactones via dienetricarbonyliron complexes

Ming Liang Lai
, Shun Chi Chang
, Chung Chen Hwu
, Ming Chang P. Yeh^*

^*此作品的通信作者

化學系

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

6 引文斯高帕斯（Scopus）

摘要

Reaction of lithium diisopropylamine (LDA) with (η⁴-1,3-buadiene)Fe(CO)₃ complexes bearing carboester functionalized side chains at C-5 gives eight- to ten-membered lactones as the major products after electrophilic quenching. However, treatments of the complexes with LDA, under an atmosphere of carbon monoxide, furnish bridged bicyclo[5.2.1]decane and bicyclo[6.2.1]undecane lactone skeletons as the major products.

原文	英語
頁（從 - 到）	6149-6152
頁數	4
期刊	Tetrahedron Letters
卷	37
發行號	34
DOIs	https://doi.org/10.1016/0040-4039(96)01334-2
出版狀態	已發佈 - 1996 8月 19

ASJC Scopus subject areas

生物化學
藥物發現
有機化學

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10.1016/0040-4039(96)01334-2

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abstract = "Reaction of lithium diisopropylamine (LDA) with (η4-1,3-buadiene)Fe(CO)3 complexes bearing carboester functionalized side chains at C-5 gives eight- to ten-membered lactones as the major products after electrophilic quenching. However, treatments of the complexes with LDA, under an atmosphere of carbon monoxide, furnish bridged bicyclo[5.2.1]decane and bicyclo[6.2.1]undecane lactone skeletons as the major products.",

author = "Lai, \{Ming Liang\} and Chang, \{Shun Chi\} and Hwu, \{Chung Chen\} and Yeh, \{Ming Chang P.\}",

year = "1996",

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doi = "10.1016/0040-4039(96)01334-2",

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AU - Lai, Ming Liang

AU - Chang, Shun Chi

AU - Hwu, Chung Chen

AU - Yeh, Ming Chang P.

PY - 1996/8/19

Y1 - 1996/8/19

N2 - Reaction of lithium diisopropylamine (LDA) with (η4-1,3-buadiene)Fe(CO)3 complexes bearing carboester functionalized side chains at C-5 gives eight- to ten-membered lactones as the major products after electrophilic quenching. However, treatments of the complexes with LDA, under an atmosphere of carbon monoxide, furnish bridged bicyclo[5.2.1]decane and bicyclo[6.2.1]undecane lactone skeletons as the major products.

AB - Reaction of lithium diisopropylamine (LDA) with (η4-1,3-buadiene)Fe(CO)3 complexes bearing carboester functionalized side chains at C-5 gives eight- to ten-membered lactones as the major products after electrophilic quenching. However, treatments of the complexes with LDA, under an atmosphere of carbon monoxide, furnish bridged bicyclo[5.2.1]decane and bicyclo[6.2.1]undecane lactone skeletons as the major products.

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SN - 0040-4039

VL - 37

SP - 6149

EP - 6152

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 34

ER -

A novel synthetic approach to medium ring lactones via dienetricarbonyliron complexes

摘要

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