A novel synthetic approach to medium ring lactones via dienetricarbonyliron complexes

Ming Liang Lai, Shun Chi Chang, Chung Chen Hwu, Ming Chang P. Yeh*

*此作品的通信作者

研究成果: 雜誌貢獻期刊論文同行評審

6 引文 斯高帕斯(Scopus)

摘要

Reaction of lithium diisopropylamine (LDA) with (η4-1,3-buadiene)Fe(CO)3 complexes bearing carboester functionalized side chains at C-5 gives eight- to ten-membered lactones as the major products after electrophilic quenching. However, treatments of the complexes with LDA, under an atmosphere of carbon monoxide, furnish bridged bicyclo[5.2.1]decane and bicyclo[6.2.1]undecane lactone skeletons as the major products.

原文英語
頁(從 - 到)6149-6152
頁數4
期刊Tetrahedron Letters
37
發行號34
DOIs
出版狀態已發佈 - 1996 8月 19

ASJC Scopus subject areas

  • 生物化學
  • 藥物發現
  • 有機化學

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