A facile synthesis of bridged-tricyclic skeletons via intramolecular Diels-Alder reaction of cyclic 1,3-dienes containing an α,β- unsaturated ester

Ming Chang P. Yeh*, Wen Cheng Tsao, Ching Jing Liu

*此作品的通信作者

研究成果: 雜誌貢獻期刊論文同行評審

3 引文 斯高帕斯(Scopus)

摘要

Intramolecular Diels-Alder reaction (IMDA) precursors are easily available starting from addition of ester functionalized zinc-copper reagents to cyclohexadienyl- and cycloheptadienylirontricarbonyl cation salts. The resulting cyclic 1,3-dienes containing an α,β-unsaturated ester functionality underwent smoothly IMDA reaction to afford bridged tricyclic compounds. Bridged heterotricyclic skeletons were also available via IMDA reaction of cyclic 1,3-dienes bearing an imine or aldehyde functionality.

原文英語
頁(從 - 到)383-387
頁數5
期刊Journal of the Chinese Chemical Society
52
發行號2
DOIs
出版狀態已發佈 - 2005 一月 1

ASJC Scopus subject areas

  • 化學 (全部)

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