A facile catalytic oxidation of activated hydrocarbons to the carbonyl functionality mediated by Mn(II) complexes

Jia Fu Pan; Kwunmin Chen

doi:10.1016/S1381-1169(01)00238-2

A facile catalytic oxidation of activated hydrocarbons to the carbonyl functionality mediated by Mn(II) complexes

Jia Fu Pan
, Kwunmin Chen^*

^*此作品的通信作者

化學系

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

37 引文斯高帕斯（Scopus）

摘要

Selective oxidation of activated hydrocarbons to the corresponding carbonyl functionality was achieved with good to high material yields using novel camphor-derived ligands mediated with Mn(II) as catalyst. In general, the reaction proceeds smoothly with 5 mol% of catalyst and 2.0 eq. of t-BuOOH as oxidant in CH₂Cl₂ in 5-30 min.

原文	英語
頁（從 - 到）	19-22
頁數	4
期刊	Journal of Molecular Catalysis A: Chemical
卷	176
發行號	1-2
DOIs	https://doi.org/10.1016/S1381-1169(01)00238-2
出版狀態	已發佈 - 2001 11月 20

ASJC Scopus subject areas

催化
製程化學與技術
物理與理論化學

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10.1016/S1381-1169(01)00238-2

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title = "A facile catalytic oxidation of activated hydrocarbons to the carbonyl functionality mediated by Mn(II) complexes",

abstract = "Selective oxidation of activated hydrocarbons to the corresponding carbonyl functionality was achieved with good to high material yields using novel camphor-derived ligands mediated with Mn(II) as catalyst. In general, the reaction proceeds smoothly with 5 mol\% of catalyst and 2.0 eq. of t-BuOOH as oxidant in CH2Cl2 in 5-30 min.",

keywords = "Catalyst, Chiral ligand, Enone, Hydrocarbon, Oxidation",

author = "Pan, \{Jia Fu\} and Kwunmin Chen",

note = "Funding Information: Financial support by the National Science Council of the Republic of China and the collection and processing of the X-ray data for ligand 1 by the Taipei Instrumentation Center, College of Science (National Taiwan University), are gratefully acknowledged. ",

year = "2001",

month = nov,

day = "20",

doi = "10.1016/S1381-1169(01)00238-2",

language = "English",

volume = "176",

pages = "19--22",

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T1 - A facile catalytic oxidation of activated hydrocarbons to the carbonyl functionality mediated by Mn(II) complexes

AU - Pan, Jia Fu

AU - Chen, Kwunmin

N1 - Funding Information: Financial support by the National Science Council of the Republic of China and the collection and processing of the X-ray data for ligand 1 by the Taipei Instrumentation Center, College of Science (National Taiwan University), are gratefully acknowledged.

PY - 2001/11/20

Y1 - 2001/11/20

N2 - Selective oxidation of activated hydrocarbons to the corresponding carbonyl functionality was achieved with good to high material yields using novel camphor-derived ligands mediated with Mn(II) as catalyst. In general, the reaction proceeds smoothly with 5 mol% of catalyst and 2.0 eq. of t-BuOOH as oxidant in CH2Cl2 in 5-30 min.

AB - Selective oxidation of activated hydrocarbons to the corresponding carbonyl functionality was achieved with good to high material yields using novel camphor-derived ligands mediated with Mn(II) as catalyst. In general, the reaction proceeds smoothly with 5 mol% of catalyst and 2.0 eq. of t-BuOOH as oxidant in CH2Cl2 in 5-30 min.

KW - Catalyst

KW - Chiral ligand

KW - Enone

KW - Hydrocarbon

KW - Oxidation

UR - https://www.scopus.com/pages/publications/0035923328

UR - https://www.scopus.com/pages/publications/0035923328#tab=citedBy

U2 - 10.1016/S1381-1169(01)00238-2

DO - 10.1016/S1381-1169(01)00238-2

M3 - Article

AN - SCOPUS:0035923328

SN - 1381-1169

VL - 176

SP - 19

EP - 22

JO - Journal of Molecular Catalysis A: Chemical

JF - Journal of Molecular Catalysis A: Chemical

IS - 1-2

ER -

A facile catalytic oxidation of activated hydrocarbons to the carbonyl functionality mediated by Mn(II) complexes

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