A facile approach to the synthesis of allylic spiro ethers and lactones

Ming Chang P. Yeh; Yi Chin Lee; Tsao Ching Young

doi:10.1055/s-2006-950294

A facile approach to the synthesis of allylic spiro ethers and lactones

Ming Chang P. Yeh^*, Yi Chin Lee, Tsao Ching Young

^*此作品的通信作者

化學系

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

16 引文斯高帕斯（Scopus）

摘要

Treatment of 3-[(alkoxycarbonyl)alkyl]-substituted conjugated cycloalkenones with diisobutylaluminum hydride at -78 °C followed by acid quenching furnishes spiro ethers, whereas the corresponding 3-(carboxyalkyl)- substituted cycloalkenones generate spiro lactones upon reaction with sodium borohydride at 30 °C followed by acid quenching.

原文	英語
頁（從 - 到）	3621-3624
頁數	4
期刊	Synthesis
發行號	21
DOIs	https://doi.org/10.1055/s-2006-950294
出版狀態	已發佈 - 2006 11月 3

ASJC Scopus subject areas

催化
有機化學

存取文件

10.1055/s-2006-950294

其它文件與鏈接

引用此

@article{9583dc167a8d4895b945d165d44b7827,

title = "A facile approach to the synthesis of allylic spiro ethers and lactones",

abstract = "Treatment of 3-[(alkoxycarbonyl)alkyl]-substituted conjugated cycloalkenones with diisobutylaluminum hydride at -78 °C followed by acid quenching furnishes spiro ethers, whereas the corresponding 3-(carboxyalkyl)- substituted cycloalkenones generate spiro lactones upon reaction with sodium borohydride at 30 °C followed by acid quenching.",

keywords = "Enones, Heterocycles, Lactones, Spiro compounds",

author = "Yeh, {Ming Chang P.} and Lee, {Yi Chin} and Young, {Tsao Ching}",

year = "2006",

month = nov,

day = "3",

doi = "10.1055/s-2006-950294",

language = "English",

pages = "3621--3624",

journal = "Synthesis (Germany)",

issn = "0039-7881",

publisher = "Georg Thieme Verlag",

number = "21",

}

TY - JOUR

T1 - A facile approach to the synthesis of allylic spiro ethers and lactones

AU - Yeh, Ming Chang P.

AU - Lee, Yi Chin

AU - Young, Tsao Ching

PY - 2006/11/3

Y1 - 2006/11/3

N2 - Treatment of 3-[(alkoxycarbonyl)alkyl]-substituted conjugated cycloalkenones with diisobutylaluminum hydride at -78 °C followed by acid quenching furnishes spiro ethers, whereas the corresponding 3-(carboxyalkyl)- substituted cycloalkenones generate spiro lactones upon reaction with sodium borohydride at 30 °C followed by acid quenching.

AB - Treatment of 3-[(alkoxycarbonyl)alkyl]-substituted conjugated cycloalkenones with diisobutylaluminum hydride at -78 °C followed by acid quenching furnishes spiro ethers, whereas the corresponding 3-(carboxyalkyl)- substituted cycloalkenones generate spiro lactones upon reaction with sodium borohydride at 30 °C followed by acid quenching.

KW - Enones

KW - Heterocycles

KW - Lactones

KW - Spiro compounds

UR - http://www.scopus.com/inward/record.url?scp=33751343665&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=33751343665&partnerID=8YFLogxK

U2 - 10.1055/s-2006-950294

DO - 10.1055/s-2006-950294

M3 - Article

AN - SCOPUS:33751343665

SP - 3621

EP - 3624

JO - Synthesis (Germany)

JF - Synthesis (Germany)

SN - 0039-7881

IS - 21

ER -

A facile approach to the synthesis of allylic spiro ethers and lactones

摘要

ASJC Scopus subject areas

存取文件

其它文件與鏈接

指紋

引用此