A discrete five-coordinate NiIII complex resembling the active site of the oxidized form of nickel superoxide dismutase

Way-Zen Lee, Chien Wei Chiang, Tsung Han Lin, Ting Shen Kuo

研究成果: 雜誌貢獻期刊論文同行評審

18 引文 斯高帕斯(Scopus)

摘要

Nickel biomimic: A pentadentate ligand, 2,6-bis(((S)-2- (diphenylhydroxymethyl)-1-pyrrolidinyl)methyl)pyridine (H2BDPP), was deprotonated and subsequently reacted with [Ni(CH3CN) 6](ClO4)2 to give Ni(BDPP) (1). A square-pyramidal NiIII complex, [Ni(BDPP)](PF6) (2), was obtained via oxidation of 1. Complex 2 can oxidize O2- into O2 and its EPR spectrum is similar to that of the oxidized form of NiSOD.

原文英語
頁(從 - 到)50-53
頁數4
期刊Chemistry - A European Journal
18
發行號1
DOIs
出版狀態已發佈 - 2012 一月 2

ASJC Scopus subject areas

  • 催化
  • 有機化學

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