摘要
The catalytic role of Cu ions in CO2 reduction on oxide-derived Cu has been elusive. In the presence of oxygen vacancy, CO⋯CO dimerization is predicted to be thermodynamically favorable with an accessible barrier on Cu4O3(202). The material's mixed valency is responsible for stabilizing the charge-separated (OC)δ+(CO)δ- intermediate.
原文 | 英語 |
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頁(從 - 到) | 16906-16909 |
頁數 | 4 |
期刊 | Physical Chemistry Chemical Physics |
卷 | 20 |
發行號 | 25 |
DOIs | |
出版狀態 | 已發佈 - 2018 |
ASJC Scopus subject areas
- 一般物理與天文學
- 物理與理論化學