2-Cyanoethylzinc iodide: A new reagent with reactivity umpolung

Ming Chang P. Yeh; Paul Knochel

doi:10.1016/S0040-4039(00)87890-9

2-Cyanoethylzinc iodide: A new reagent with reactivity umpolung

Ming Chang P. Yeh^*, Paul Knochel

^*此作品的通信作者

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

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摘要

2-Cyanoethylzinc iodide 1 generated in over 90% yield from 3-iodopropionitrile and zinc in THF can be transmetallated to the copper and titanium derivatives 3 and 4 which react in good yields, respectively, with acyl chlorides, enones, allylic halides and benzaldehyde.

原文	英語
頁（從 - 到）	2395-2396
頁數	2
期刊	Tetrahedron Letters
卷	29
發行號	20
DOIs	https://doi.org/10.1016/S0040-4039(00)87890-9
出版狀態	已發佈 - 1988
對外發佈	是

ASJC Scopus subject areas

生物化學
藥物發現
有機化學

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10.1016/S0040-4039(00)87890-9

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title = "2-Cyanoethylzinc iodide: A new reagent with reactivity umpolung",

abstract = "2-Cyanoethylzinc iodide 1 generated in over 90% yield from 3-iodopropionitrile and zinc in THF can be transmetallated to the copper and titanium derivatives 3 and 4 which react in good yields, respectively, with acyl chlorides, enones, allylic halides and benzaldehyde.",

author = "Yeh, {Ming Chang P.} and Paul Knochel",

year = "1988",

doi = "10.1016/S0040-4039(00)87890-9",

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T1 - 2-Cyanoethylzinc iodide

T2 - A new reagent with reactivity umpolung

AU - Yeh, Ming Chang P.

AU - Knochel, Paul

PY - 1988

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N2 - 2-Cyanoethylzinc iodide 1 generated in over 90% yield from 3-iodopropionitrile and zinc in THF can be transmetallated to the copper and titanium derivatives 3 and 4 which react in good yields, respectively, with acyl chlorides, enones, allylic halides and benzaldehyde.

AB - 2-Cyanoethylzinc iodide 1 generated in over 90% yield from 3-iodopropionitrile and zinc in THF can be transmetallated to the copper and titanium derivatives 3 and 4 which react in good yields, respectively, with acyl chlorides, enones, allylic halides and benzaldehyde.

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U2 - 10.1016/S0040-4039(00)87890-9

DO - 10.1016/S0040-4039(00)87890-9

M3 - Article

AN - SCOPUS:0000399484

VL - 29

SP - 2395

EP - 2396

JO - Tetrahedron Letters

JF - Tetrahedron Letters

SN - 0040-4039

IS - 20

ER -

2-Cyanoethylzinc iodide: A new reagent with reactivity umpolung

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