[1,4-Bis(diphenylphosphanyl)butane-κ2P,P′] chlorido(η5-indenyl)ruthenium(II)

Hui Ling Sung; Tze Min Her; Wen Hsien Su; Chin Pao Cheng

doi:10.1107/S1600536811015121

[1,4-Bis(diphenylphosphanyl)butane-κ²P,P′] chlorido(η⁵-indenyl)ruthenium(II)

Hui Ling Sung^*, Tze Min Her, Wen Hsien Su, Chin Pao Cheng

^*此作品的通信作者

機電工程學系

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

1 引文斯高帕斯（Scopus）

摘要

Facile ligand substitution is observed when the ruthenium chloride complex [Ru(η⁵-C₉H₇)Cl(PPh₃) ₂] is treated with 1,4-bis(diphenylphosphanyl)butane in refluxing toluene yielding the title compound, [Ru(C₉H₇)Cl(C ₂₈H₂₈P₂)]. The Ru^II atom has a typical piano-stool coordination, defined by the indenyl ligand, one Cl atom and two phosphanyl P atoms. The Ru-P bond lengths are 2.2502 (9) and 2.2968 (8) Å.

原文	英語
頁（從 - 到）	m641
期刊	Acta Crystallographica Section E: Structure Reports Online
卷	67
發行號	5
DOIs	https://doi.org/10.1107/S1600536811015121
出版狀態	已發佈 - 2011 5月

ASJC Scopus subject areas

一般化學
一般材料科學
凝聚態物理學

存取文件

10.1107/S1600536811015121

其它文件與鏈接

CCDC 825346: Experimental Crystal Structure Determination
Sung, H. (Creator), Her, T. (Creator), Su, W. (Creator) & Cheng, C. (Creator), Cambridge Crystallographic Data Centre, 2011
DOI: 10.5517/ccwpv2g, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccwpv2g&sid=DataCite
資料集: Dataset

引用此

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title = "[1,4-Bis(diphenylphosphanyl)butane-κ2P,P′] chlorido(η5-indenyl)ruthenium(II)",

abstract = "Facile ligand substitution is observed when the ruthenium chloride complex [Ru(η5-C9H7)Cl(PPh3) 2] is treated with 1,4-bis(diphenylphosphanyl)butane in refluxing toluene yielding the title compound, [Ru(C9H7)Cl(C 28H28P2)]. The RuII atom has a typical piano-stool coordination, defined by the indenyl ligand, one Cl atom and two phosphanyl P atoms. The Ru-P bond lengths are 2.2502 (9) and 2.2968 (8) {\AA}.",

author = "Sung, {Hui Ling} and Her, {Tze Min} and Su, {Wen Hsien} and Cheng, {Chin Pao}",

year = "2011",

month = may,

doi = "10.1107/S1600536811015121",

language = "English",

volume = "67",

pages = "m641",

journal = "Acta Crystallographica Section E: Structure Reports Online",

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publisher = "International Union of Crystallography",

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T1 - [1,4-Bis(diphenylphosphanyl)butane-κ2P,P′] chlorido(η5-indenyl)ruthenium(II)

AU - Sung, Hui Ling

AU - Her, Tze Min

AU - Su, Wen Hsien

AU - Cheng, Chin Pao

PY - 2011/5

Y1 - 2011/5

N2 - Facile ligand substitution is observed when the ruthenium chloride complex [Ru(η5-C9H7)Cl(PPh3) 2] is treated with 1,4-bis(diphenylphosphanyl)butane in refluxing toluene yielding the title compound, [Ru(C9H7)Cl(C 28H28P2)]. The RuII atom has a typical piano-stool coordination, defined by the indenyl ligand, one Cl atom and two phosphanyl P atoms. The Ru-P bond lengths are 2.2502 (9) and 2.2968 (8) Å.

AB - Facile ligand substitution is observed when the ruthenium chloride complex [Ru(η5-C9H7)Cl(PPh3) 2] is treated with 1,4-bis(diphenylphosphanyl)butane in refluxing toluene yielding the title compound, [Ru(C9H7)Cl(C 28H28P2)]. The RuII atom has a typical piano-stool coordination, defined by the indenyl ligand, one Cl atom and two phosphanyl P atoms. The Ru-P bond lengths are 2.2502 (9) and 2.2968 (8) Å.

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U2 - 10.1107/S1600536811015121

DO - 10.1107/S1600536811015121

M3 - Article

AN - SCOPUS:79955611162

SN - 1600-5368

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SP - m641

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 5

ER -

[1,4-Bis(diphenylphosphanyl)butane-κ2P,P′] chlorido(η5-indenyl)ruthenium(II)

摘要

ASJC Scopus subject areas

存取文件

其它文件與鏈接

指紋

資料集

CCDC 825346: Experimental Crystal Structure Determination

引用此

[1,4-Bis(diphenylphosphanyl)butane-κ²P,P′] chlorido(η⁵-indenyl)ruthenium(II)