1,3-Diphenyl-2-tricyclo[3.3.1.1 3,7]dec-2-ylidenepropane-l,3-diimine, and its -1-imino-3-one and -1,3-dione derivatives

Ching Fa Yao*, Yuh Shih Chen, Wen Chang Chen, Ren Shyang Sheu, Jen Kou Lai, Chuen Her Ueng

*此作品的通信作者

研究成果: 雜誌貢獻期刊論文同行評審

2 引文 斯高帕斯(Scopus)

摘要

1,3-Diphenyl-2-tricyclo[3.3.1.1 3,7]dec-2-ylidenepropane-1,3-diimine, C25H26N2, (1), 1-imino-1,3-diphenyl-2-tricyclo[3.3.1.13,7]dec-2-ylidenepropan-3-one, C25H25NO, (2) and 1,3-diphenyl-2-tricyclo[3.3.1.13,7]dec-2-ylidenepropane-1,3-dione, C25H24O2, (3), were prepared from the reactions of 2-(dicyanomethylene)adamantane with phenylmagnesium bromide upon workup with dry methanol or dilute acid aqueous solution, and their crystal structures were determined by X-ray diffraction. Compounds (1) and (2) have similar molecular structures with the two imino groups in (1) and the imino and ketone groups in (2) being on the same side of the C1, C2, C12, C13 plane, compared with the two O atoms in compound (3), which are on opposite sides.

原文英語
頁(從 - 到)956-959
頁數4
期刊Acta Crystallographica Section C: Crystal Structure Communications
53
發行號7
DOIs
出版狀態已發佈 - 1997 七月 15

ASJC Scopus subject areas

  • 生物化學、遺傳與分子生物學 (全部)

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