Versatile reactions on hydrophobic functionalization of metal-organic frameworks and anticorrosion application

Bing Han Li; Sue Lein Wang; Souvik Pal; Pamela Berilyn So; Guan Ying Chen; Wei Jie Huang; Yu Ling Hsu; Szu Yu Kuo; Jui Ming Yeh; Chia Her Lin

doi:10.1016/j.micromeso.2021.111319

Versatile reactions on hydrophobic functionalization of metal-organic frameworks and anticorrosion application

Bing Han Li, Sue Lein Wang^*, Souvik Pal, Pamela Berilyn So, Guan Ying Chen, Wei Jie Huang, Yu Ling Hsu, Szu Yu Kuo, Jui Ming Yeh^*, Chia Her Lin^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

Four post-synthetic modification (PSM) reactions to incorporate alkyl chains onto metal-organic frameworks (MOFs) were explored by using various organic transformation reactions. The modified hydrophobic MOFs can reduce the interface voids within the MOF-polymer composites. In this work, it was demonstrated that the decorated hydrophobic MOFs eliminated the interfacial voids in the MOF-polyaniline (PANI) composites and increased the anticorrosion performance. In particular, PAZr-C₁₈-5% composite exhibited significant anticorrosive properties as the corrosion current density was reduced from 71.61 to 0.18 μA/cm². Furthermore, the doping of hydrophobic MOFs into PANI can also increases the composite's surface hydrophobicity and improve its gas barrier performance.

Original language	English
Article number	111319
Journal	Microporous and Mesoporous Materials
Volume	325
DOIs	https://doi.org/10.1016/j.micromeso.2021.111319
Publication status	Published - 2021 Oct

Keywords

Anticorrosion
Hydrophobic
Metal-organic frameworks
Polyaniline
Post-synthetic modification

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics
Mechanics of Materials

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10.1016/j.micromeso.2021.111319

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@article{90d8c9820c23425b84f458c3feb610fd,

title = "Versatile reactions on hydrophobic functionalization of metal-organic frameworks and anticorrosion application",

abstract = "Four post-synthetic modification (PSM) reactions to incorporate alkyl chains onto metal-organic frameworks (MOFs) were explored by using various organic transformation reactions. The modified hydrophobic MOFs can reduce the interface voids within the MOF-polymer composites. In this work, it was demonstrated that the decorated hydrophobic MOFs eliminated the interfacial voids in the MOF-polyaniline (PANI) composites and increased the anticorrosion performance. In particular, PAZr-C18-5% composite exhibited significant anticorrosive properties as the corrosion current density was reduced from 71.61 to 0.18 μA/cm2. Furthermore, the doping of hydrophobic MOFs into PANI can also increases the composite's surface hydrophobicity and improve its gas barrier performance.",

keywords = "Anticorrosion, Hydrophobic, Metal-organic frameworks, Polyaniline, Post-synthetic modification",

author = "Li, {Bing Han} and Wang, {Sue Lein} and Souvik Pal and So, {Pamela Berilyn} and Chen, {Guan Ying} and Huang, {Wei Jie} and Hsu, {Yu Ling} and Kuo, {Szu Yu} and Yeh, {Jui Ming} and Lin, {Chia Her}",

note = "Publisher Copyright: {\textcopyright} 2021 Elsevier Inc.",

year = "2021",

month = oct,

doi = "10.1016/j.micromeso.2021.111319",

language = "English",

volume = "325",

journal = "Microporous and Mesoporous Materials",

issn = "1387-1811",

publisher = "Elsevier",

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TY - JOUR

T1 - Versatile reactions on hydrophobic functionalization of metal-organic frameworks and anticorrosion application

AU - Li, Bing Han

AU - Wang, Sue Lein

AU - Pal, Souvik

AU - So, Pamela Berilyn

AU - Chen, Guan Ying

AU - Huang, Wei Jie

AU - Hsu, Yu Ling

AU - Kuo, Szu Yu

AU - Yeh, Jui Ming

AU - Lin, Chia Her

PY - 2021/10

Y1 - 2021/10

N2 - Four post-synthetic modification (PSM) reactions to incorporate alkyl chains onto metal-organic frameworks (MOFs) were explored by using various organic transformation reactions. The modified hydrophobic MOFs can reduce the interface voids within the MOF-polymer composites. In this work, it was demonstrated that the decorated hydrophobic MOFs eliminated the interfacial voids in the MOF-polyaniline (PANI) composites and increased the anticorrosion performance. In particular, PAZr-C18-5% composite exhibited significant anticorrosive properties as the corrosion current density was reduced from 71.61 to 0.18 μA/cm2. Furthermore, the doping of hydrophobic MOFs into PANI can also increases the composite's surface hydrophobicity and improve its gas barrier performance.

AB - Four post-synthetic modification (PSM) reactions to incorporate alkyl chains onto metal-organic frameworks (MOFs) were explored by using various organic transformation reactions. The modified hydrophobic MOFs can reduce the interface voids within the MOF-polymer composites. In this work, it was demonstrated that the decorated hydrophobic MOFs eliminated the interfacial voids in the MOF-polyaniline (PANI) composites and increased the anticorrosion performance. In particular, PAZr-C18-5% composite exhibited significant anticorrosive properties as the corrosion current density was reduced from 71.61 to 0.18 μA/cm2. Furthermore, the doping of hydrophobic MOFs into PANI can also increases the composite's surface hydrophobicity and improve its gas barrier performance.

KW - Anticorrosion

KW - Hydrophobic

KW - Metal-organic frameworks

KW - Polyaniline

KW - Post-synthetic modification

UR - http://www.scopus.com/inward/record.url?scp=85112350340&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85112350340&partnerID=8YFLogxK

U2 - 10.1016/j.micromeso.2021.111319

DO - 10.1016/j.micromeso.2021.111319

M3 - Article

AN - SCOPUS:85112350340

SN - 1387-1811

VL - 325

JO - Microporous and Mesoporous Materials

JF - Microporous and Mesoporous Materials

M1 - 111319

ER -

Versatile reactions on hydrophobic functionalization of metal-organic frameworks and anticorrosion application

Abstract

Keywords

ASJC Scopus subject areas

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