Vapor sensing mechanism studies for monolayer protected gold nano-clusters on QCM and chemiresistor transducers

Rih Sheng Jian, Chia Jung Tsai, Lung Yu Sung, Chia Jung Lu

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

This research reports a series of monolayer-protected gold nano-clusters (MPCs) with various organo-thiolate groups capped and coated onto both chemiresistor (CR) and quartz crystal microbalance (QCM) transducers as chemical sensors for the detection of airborne volatile organic compounds (VOCs). The three thiolates that were used to encapsulate nano-gold were 1-octanethiol (Au-C8), 4-tert-butylbenzenethiol (Au-TBT), and a mixture of both (Au-C8TBT). The vapor responses using MPC sensing film on both QCM and CR transducers were rapid, reversible, and linear (R 2 > 0.99). The Au-C8-coated sensors represented the well known sensing behavior, which holds that sorption mass and resistance changes are correlated. The Au-TBT sensor showed the opposite - a high sorption mass for a QCM signal but virtually no change in resistance for CR. This result contradicts the conventional belief that the degree of resistance change is proportional to the absorbed mass. The mixed-ligand Au-C8TBT film showed alternative vapor selectivity for both CR and QCM transducers that deviated from both Au-C8 and Au-TBT film. The chemical structures of the mechanisms for vapor selectivity for two different transducers were investigated and are discussed here.

Original languageEnglish
Title of host publicationIEEE Sensors 2011 Conference, SENSORS 2011
Pages732-735
Number of pages4
DOIs
Publication statusPublished - 2011 Dec 1
Event10th IEEE SENSORS Conference 2011, SENSORS 2011 - Limerick, Ireland
Duration: 2011 Oct 282011 Oct 31

Other

Other10th IEEE SENSORS Conference 2011, SENSORS 2011
CountryIreland
CityLimerick
Period11/10/2811/10/31

Fingerprint

Quartz crystal microbalances
Transducers
Monolayers
Gold
Vapors
Sorption
Sensors
Chemical sensors
Volatile organic compounds
Ligands

ASJC Scopus subject areas

  • Electrical and Electronic Engineering

Cite this

Jian, R. S., Tsai, C. J., Sung, L. Y., & Lu, C. J. (2011). Vapor sensing mechanism studies for monolayer protected gold nano-clusters on QCM and chemiresistor transducers. In IEEE Sensors 2011 Conference, SENSORS 2011 (pp. 732-735). [6126952] https://doi.org/10.1109/ICSENS.2011.6126952

Vapor sensing mechanism studies for monolayer protected gold nano-clusters on QCM and chemiresistor transducers. / Jian, Rih Sheng; Tsai, Chia Jung; Sung, Lung Yu; Lu, Chia Jung.

IEEE Sensors 2011 Conference, SENSORS 2011. 2011. p. 732-735 6126952.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Jian, RS, Tsai, CJ, Sung, LY & Lu, CJ 2011, Vapor sensing mechanism studies for monolayer protected gold nano-clusters on QCM and chemiresistor transducers. in IEEE Sensors 2011 Conference, SENSORS 2011., 6126952, pp. 732-735, 10th IEEE SENSORS Conference 2011, SENSORS 2011, Limerick, Ireland, 11/10/28. https://doi.org/10.1109/ICSENS.2011.6126952
Jian, Rih Sheng ; Tsai, Chia Jung ; Sung, Lung Yu ; Lu, Chia Jung. / Vapor sensing mechanism studies for monolayer protected gold nano-clusters on QCM and chemiresistor transducers. IEEE Sensors 2011 Conference, SENSORS 2011. 2011. pp. 732-735
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