Vapochemically and mechanochemically reversible polymerization/depolymerization of S–Fe–Cu carbonyl clusters

Chien Nan Lin; Wei Ting Jhu; Minghuey Shieh

doi:10.1039/c3cc48303g

Vapochemically and mechanochemically reversible polymerization/depolymerization of S–Fe–Cu carbonyl clusters

Chien Nan Lin, Wei Ting Jhu, Minghuey Shieh^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

A reversible vapochemical and mechanochemical solid-state transformation between a dppe-linked SFe₃Cu₂-based cluster [((μ₃-S)Fe₃(CO)₉)Cu₂(dppe)] (2) and its 1D polymer [((μ₄-S)Fe₃(CO)₉)Cu₂(dppe)(MeCN)₂]_n (3) was demonstrated, in which polymer 3 exhibited semi-conducting properties with an energy gap of 1.69 eV.

Original language	English
Pages (from-to)	1134-1136
Number of pages	3
Journal	Chemical Communications
Volume	50
Issue number	9
DOIs	https://doi.org/10.1039/c3cc48303g
Publication status	Published - 2014 Dec 24

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c3cc48303g

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title = "Vapochemically and mechanochemically reversible polymerization/depolymerization of S–Fe–Cu carbonyl clusters",

abstract = "A reversible vapochemical and mechanochemical solid-state transformation between a dppe-linked SFe3Cu2-based cluster [((μ3-S)Fe3(CO)9)Cu2(dppe)] (2) and its 1D polymer [((μ4-S)Fe3(CO)9)Cu2(dppe)(MeCN)2]n (3) was demonstrated, in which polymer 3 exhibited semi-conducting properties with an energy gap of 1.69 eV.",

author = "Lin, {Chien Nan} and Jhu, {Wei Ting} and Minghuey Shieh",

year = "2014",

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language = "English",

volume = "50",

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journal = "Chemical Communications",

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T1 - Vapochemically and mechanochemically reversible polymerization/depolymerization of S–Fe–Cu carbonyl clusters

AU - Lin, Chien Nan

AU - Jhu, Wei Ting

AU - Shieh, Minghuey

PY - 2014/12/24

Y1 - 2014/12/24

N2 - A reversible vapochemical and mechanochemical solid-state transformation between a dppe-linked SFe3Cu2-based cluster [((μ3-S)Fe3(CO)9)Cu2(dppe)] (2) and its 1D polymer [((μ4-S)Fe3(CO)9)Cu2(dppe)(MeCN)2]n (3) was demonstrated, in which polymer 3 exhibited semi-conducting properties with an energy gap of 1.69 eV.

AB - A reversible vapochemical and mechanochemical solid-state transformation between a dppe-linked SFe3Cu2-based cluster [((μ3-S)Fe3(CO)9)Cu2(dppe)] (2) and its 1D polymer [((μ4-S)Fe3(CO)9)Cu2(dppe)(MeCN)2]n (3) was demonstrated, in which polymer 3 exhibited semi-conducting properties with an energy gap of 1.69 eV.

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JO - Chemical Communications

JF - Chemical Communications

IS - 9

ER -

Vapochemically and mechanochemically reversible polymerization/depolymerization of S–Fe–Cu carbonyl clusters

Abstract

ASJC Scopus subject areas

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CCDC 930775: Experimental Crystal Structure Determination

CCDC 930776: Experimental Crystal Structure Determination

CCDC 930774: Experimental Crystal Structure Determination

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Vapochemically and mechanochemically reversible polymerization/depolymerization of S–Fe–Cu carbonyl clusters

Abstract

ASJC Scopus subject areas

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Datasets

CCDC 930775: Experimental Crystal Structure Determination

CCDC 930776: Experimental Crystal Structure Determination

CCDC 930774: Experimental Crystal Structure Determination

Cite this