Vapochemically and mechanochemically reversible polymerization/depolymerization of S–Fe–Cu carbonyl clusters

Chien Nan Lin, Wei Ting Jhu, Minghuey Shieh

Research output: Contribution to journalArticlepeer-review

6 Citations (Scopus)

Abstract

A reversible vapochemical and mechanochemical solid-state transformation between a dppe-linked SFe3Cu2-based cluster [((μ3-S)Fe3(CO)9)Cu2(dppe)] (2) and its 1D polymer [((μ4-S)Fe3(CO)9)Cu2(dppe)(MeCN)2]n (3) was demonstrated, in which polymer 3 exhibited semi-conducting properties with an energy gap of 1.69 eV.

Original languageEnglish
Pages (from-to)1134-1136
Number of pages3
JournalChemical Communications
Volume50
Issue number9
DOIs
Publication statusPublished - 2014 Dec 24

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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