Triethylborane-induced free radical reactions with benzylidene Meldrum's acids. simple and efficient synthesis of benzyl Meldrum's acids

Shijay Gao; Tingkai Tzeng; Ying Tsang Lan; Ju Tsung Liu; Ching Fa Yao

doi:10.3998/ark.5550190.0010.c30

Triethylborane-induced free radical reactions with benzylidene Meldrum's acids. simple and efficient synthesis of benzyl Meldrum's acids

Shijay Gao
, Tingkai Tzeng
, Ying Tsang Lan
, Ju Tsung Liu
, Ching Fa Yao^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

We have developed a simple aerobic synthesis of benzyl Meldrum's acids from benzylidene Meldrum's acids with Et ₃B or RI/Et ₃B. The reaction system has also been applied successfully to the synthesis of benzyl Meldrum's acids in a one-pot procedure.

Original language	English
Pages (from-to)	347-361
Number of pages	15
Journal	Arkivoc
Volume	2009
Issue number	12
DOIs	https://doi.org/10.3998/ark.5550190.0010.c30
Publication status	Published - 2009

Keywords

Benzyl Meldrum's acid
Benzylidene Meldrum's acid
Free radical
Meldrum's acid
Triethylborane

ASJC Scopus subject areas

Organic Chemistry

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10.3998/ark.5550190.0010.c30

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title = "Triethylborane-induced free radical reactions with benzylidene Meldrum's acids. simple and efficient synthesis of benzyl Meldrum's acids",

abstract = "We have developed a simple aerobic synthesis of benzyl Meldrum's acids from benzylidene Meldrum's acids with Et 3B or RI/Et 3B. The reaction system has also been applied successfully to the synthesis of benzyl Meldrum's acids in a one-pot procedure.",

keywords = "Benzyl Meldrum's acid, Benzylidene Meldrum's acid, Free radical, Meldrum's acid, Triethylborane",

author = "Shijay Gao and Tingkai Tzeng and Lan, \{Ying Tsang\} and Liu, \{Ju Tsung\} and Yao, \{Ching Fa\}",

year = "2009",

doi = "10.3998/ark.5550190.0010.c30",

language = "English",

volume = "2009",

pages = "347--361",

journal = "Arkivoc",

issn = "1551-7012",

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number = "12",

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T1 - Triethylborane-induced free radical reactions with benzylidene Meldrum's acids. simple and efficient synthesis of benzyl Meldrum's acids

AU - Gao, Shijay

AU - Tzeng, Tingkai

AU - Lan, Ying Tsang

AU - Liu, Ju Tsung

AU - Yao, Ching Fa

PY - 2009

Y1 - 2009

N2 - We have developed a simple aerobic synthesis of benzyl Meldrum's acids from benzylidene Meldrum's acids with Et 3B or RI/Et 3B. The reaction system has also been applied successfully to the synthesis of benzyl Meldrum's acids in a one-pot procedure.

AB - We have developed a simple aerobic synthesis of benzyl Meldrum's acids from benzylidene Meldrum's acids with Et 3B or RI/Et 3B. The reaction system has also been applied successfully to the synthesis of benzyl Meldrum's acids in a one-pot procedure.

KW - Benzyl Meldrum's acid

KW - Benzylidene Meldrum's acid

KW - Free radical

KW - Meldrum's acid

KW - Triethylborane

UR - https://www.scopus.com/pages/publications/77953228678

UR - https://www.scopus.com/pages/publications/77953228678#tab=citedBy

U2 - 10.3998/ark.5550190.0010.c30

DO - 10.3998/ark.5550190.0010.c30

M3 - Article

AN - SCOPUS:77953228678

SN - 1551-7012

VL - 2009

SP - 347

EP - 361

JO - Arkivoc

JF - Arkivoc

IS - 12

ER -

Triethylborane-induced free radical reactions with benzylidene Meldrum's acids. simple and efficient synthesis of benzyl Meldrum's acids

Abstract

Keywords

ASJC Scopus subject areas

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