Triethylborane-induced free radical reactions with benzylidene Meldrum's acids. simple and efficient synthesis of benzyl Meldrum's acids

Shijay Gao; Tingkai Tzeng; Ying Tsang Lan; Ju Tsung Liu; Ching Fa Yao

doi:10.3998/ark.5550190.0010.c30

Triethylborane-induced free radical reactions with benzylidene Meldrum's acids. simple and efficient synthesis of benzyl Meldrum's acids

Shijay Gao, Tingkai Tzeng, Ying Tsang Lan, Ju Tsung Liu, Ching Fa Yao^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

We have developed a simple aerobic synthesis of benzyl Meldrum's acids from benzylidene Meldrum's acids with Et ₃B or RI/Et ₃B. The reaction system has also been applied successfully to the synthesis of benzyl Meldrum's acids in a one-pot procedure.

Original language	English
Pages (from-to)	347-361
Number of pages	15
Journal	Arkivoc
Volume	2009
Issue number	12
DOIs	https://doi.org/10.3998/ark.5550190.0010.c30
Publication status	Published - 2009

Keywords

Benzyl Meldrum's acid
Benzylidene Meldrum's acid
Free radical
Meldrum's acid
Triethylborane

ASJC Scopus subject areas

Organic Chemistry

Access to Document

10.3998/ark.5550190.0010.c30

Cite this

@article{7d8d4468203142dcaedf6605ad6be93c,

title = "Triethylborane-induced free radical reactions with benzylidene Meldrum's acids. simple and efficient synthesis of benzyl Meldrum's acids",

abstract = "We have developed a simple aerobic synthesis of benzyl Meldrum's acids from benzylidene Meldrum's acids with Et 3B or RI/Et 3B. The reaction system has also been applied successfully to the synthesis of benzyl Meldrum's acids in a one-pot procedure.",

keywords = "Benzyl Meldrum's acid, Benzylidene Meldrum's acid, Free radical, Meldrum's acid, Triethylborane",

author = "Shijay Gao and Tingkai Tzeng and Lan, {Ying Tsang} and Liu, {Ju Tsung} and Yao, {Ching Fa}",

year = "2009",

doi = "10.3998/ark.5550190.0010.c30",

language = "English",

volume = "2009",

pages = "347--361",

journal = "Arkivoc",

issn = "1551-7012",

publisher = "Arkat USA",

number = "12",

}

TY - JOUR

T1 - Triethylborane-induced free radical reactions with benzylidene Meldrum's acids. simple and efficient synthesis of benzyl Meldrum's acids

AU - Gao, Shijay

AU - Tzeng, Tingkai

AU - Lan, Ying Tsang

AU - Liu, Ju Tsung

AU - Yao, Ching Fa

PY - 2009

Y1 - 2009

N2 - We have developed a simple aerobic synthesis of benzyl Meldrum's acids from benzylidene Meldrum's acids with Et 3B or RI/Et 3B. The reaction system has also been applied successfully to the synthesis of benzyl Meldrum's acids in a one-pot procedure.

AB - We have developed a simple aerobic synthesis of benzyl Meldrum's acids from benzylidene Meldrum's acids with Et 3B or RI/Et 3B. The reaction system has also been applied successfully to the synthesis of benzyl Meldrum's acids in a one-pot procedure.

KW - Benzyl Meldrum's acid

KW - Benzylidene Meldrum's acid

KW - Free radical

KW - Meldrum's acid

KW - Triethylborane

UR - http://www.scopus.com/inward/record.url?scp=77953228678&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=77953228678&partnerID=8YFLogxK

U2 - 10.3998/ark.5550190.0010.c30

DO - 10.3998/ark.5550190.0010.c30

M3 - Article

AN - SCOPUS:77953228678

SN - 1551-7012

VL - 2009

SP - 347

EP - 361

JO - Arkivoc

JF - Arkivoc

IS - 12

ER -

Triethylborane-induced free radical reactions with benzylidene Meldrum's acids. simple and efficient synthesis of benzyl Meldrum's acids

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this