Trapping of tricarbonyl(η1,η2-homoallyl)iron and tricarbonyl(η3-allyl)iron anion intermediates with 2-(phenylsulfonyl)-3-phenyloxaziridine

Ming Chang P. Yeh; Jin Xuan Ho; Peng Yu Hsueh

doi:10.1002/jccs.200300116

Trapping of tricarbonyl(η¹,η²-homoallyl)iron and tricarbonyl(η³-allyl)iron anion intermediates with 2-(phenylsulfonyl)-3-phenyloxaziridine

Ming Chang P. Yeh^*, Jin Xuan Ho, Peng Yu Hsueh

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

The addition of reactive carbanions to (η⁴-1,3-diene)Fe(CO) ₃ complexes at -78 °C and 25 °C produced putative homoallyl and allyl anion complexes, respectively. Reaction of the reactive intermediates with 2-(phenylsulfonyl)-3-phenyloxaziridine afforded nucleophilic substituted (η⁴-1,3-diene)Fe(CO)₃ complexes.

Original language	English
Pages (from-to)	833-840
Number of pages	8
Journal	Journal of the Chinese Chemical Society
Volume	50
Issue number	4
DOIs	https://doi.org/10.1002/jccs.200300116
Publication status	Published - 2003

Keywords

Davis reagent
Diene
Hydride
Iron

ASJC Scopus subject areas

General Chemistry

Access to Document

10.1002/jccs.200300116

Cite this

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title = "Trapping of tricarbonyl(η1,η2-homoallyl)iron and tricarbonyl(η3-allyl)iron anion intermediates with 2-(phenylsulfonyl)-3-phenyloxaziridine",

abstract = "The addition of reactive carbanions to (η4-1,3-diene)Fe(CO) 3 complexes at -78 °C and 25 °C produced putative homoallyl and allyl anion complexes, respectively. Reaction of the reactive intermediates with 2-(phenylsulfonyl)-3-phenyloxaziridine afforded nucleophilic substituted (η4-1,3-diene)Fe(CO)3 complexes.",

keywords = "Davis reagent, Diene, Hydride, Iron",

author = "Yeh, {Ming Chang P.} and Ho, {Jin Xuan} and Hsueh, {Peng Yu}",

year = "2003",

doi = "10.1002/jccs.200300116",

language = "English",

volume = "50",

pages = "833--840",

journal = "Journal of the Chinese Chemical Society",

issn = "0009-4536",

publisher = "Chinese Chemical Society",

number = "4",

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T1 - Trapping of tricarbonyl(η1,η2-homoallyl)iron and tricarbonyl(η3-allyl)iron anion intermediates with 2-(phenylsulfonyl)-3-phenyloxaziridine

AU - Yeh, Ming Chang P.

AU - Ho, Jin Xuan

AU - Hsueh, Peng Yu

PY - 2003

Y1 - 2003

N2 - The addition of reactive carbanions to (η4-1,3-diene)Fe(CO) 3 complexes at -78 °C and 25 °C produced putative homoallyl and allyl anion complexes, respectively. Reaction of the reactive intermediates with 2-(phenylsulfonyl)-3-phenyloxaziridine afforded nucleophilic substituted (η4-1,3-diene)Fe(CO)3 complexes.

AB - The addition of reactive carbanions to (η4-1,3-diene)Fe(CO) 3 complexes at -78 °C and 25 °C produced putative homoallyl and allyl anion complexes, respectively. Reaction of the reactive intermediates with 2-(phenylsulfonyl)-3-phenyloxaziridine afforded nucleophilic substituted (η4-1,3-diene)Fe(CO)3 complexes.

KW - Davis reagent

KW - Diene

KW - Hydride

KW - Iron

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U2 - 10.1002/jccs.200300116

DO - 10.1002/jccs.200300116

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SP - 833

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JF - Journal of the Chinese Chemical Society

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