Trapping of tricarbonyl(η12-homoallyl)iron and tricarbonyl(η3-allyl)iron anion intermediates with 2-(phenylsulfonyl)-3-phenyloxaziridine

Ming Chang P. Yeh, Jin Xuan Ho, Peng Yu Hsueh

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

The addition of reactive carbanions to (η4-1,3-diene)Fe(CO) 3 complexes at -78 °C and 25 °C produced putative homoallyl and allyl anion complexes, respectively. Reaction of the reactive intermediates with 2-(phenylsulfonyl)-3-phenyloxaziridine afforded nucleophilic substituted (η4-1,3-diene)Fe(CO)3 complexes.

Original languageEnglish
Pages (from-to)833-840
Number of pages8
JournalJournal of the Chinese Chemical Society
Volume50
Issue number4
DOIs
Publication statusPublished - 2003 Jan 1

Keywords

  • Davis reagent
  • Diene
  • Hydride
  • Iron

ASJC Scopus subject areas

  • Chemistry(all)

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