Trapping of tricarbonyl(η12-homoallyl)iron and tricarbonyl(η3-allyl)iron anion intermediates with 2-(phenylsulfonyl)-3-phenyloxaziridine

Ming-Chang P. Yeh, Jin Xuan Ho, Peng Yu Hsueh

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

The addition of reactive carbanions to (η4-1,3-diene)Fe(CO) 3 complexes at -78 °C and 25 °C produced putative homoallyl and allyl anion complexes, respectively. Reaction of the reactive intermediates with 2-(phenylsulfonyl)-3-phenyloxaziridine afforded nucleophilic substituted (η4-1,3-diene)Fe(CO)3 complexes.

Original languageEnglish
Pages (from-to)833-840
Number of pages8
JournalJournal of the Chinese Chemical Society
Volume50
Issue number4
DOIs
Publication statusPublished - 2003 Jan 1

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Carbon Monoxide
Anions
Iron

Keywords

  • Davis reagent
  • Diene
  • Hydride
  • Iron

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

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title = "Trapping of tricarbonyl(η1,η2-homoallyl)iron and tricarbonyl(η3-allyl)iron anion intermediates with 2-(phenylsulfonyl)-3-phenyloxaziridine",
abstract = "The addition of reactive carbanions to (η4-1,3-diene)Fe(CO) 3 complexes at -78 °C and 25 °C produced putative homoallyl and allyl anion complexes, respectively. Reaction of the reactive intermediates with 2-(phenylsulfonyl)-3-phenyloxaziridine afforded nucleophilic substituted (η4-1,3-diene)Fe(CO)3 complexes.",
keywords = "Davis reagent, Diene, Hydride, Iron",
author = "Yeh, {Ming-Chang P.} and Ho, {Jin Xuan} and Hsueh, {Peng Yu}",
year = "2003",
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language = "English",
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journal = "Journal of the Chinese Chemical Society",
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publisher = "Chinese Chemical Society",
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T1 - Trapping of tricarbonyl(η1,η2-homoallyl)iron and tricarbonyl(η3-allyl)iron anion intermediates with 2-(phenylsulfonyl)-3-phenyloxaziridine

AU - Yeh, Ming-Chang P.

AU - Ho, Jin Xuan

AU - Hsueh, Peng Yu

PY - 2003/1/1

Y1 - 2003/1/1

N2 - The addition of reactive carbanions to (η4-1,3-diene)Fe(CO) 3 complexes at -78 °C and 25 °C produced putative homoallyl and allyl anion complexes, respectively. Reaction of the reactive intermediates with 2-(phenylsulfonyl)-3-phenyloxaziridine afforded nucleophilic substituted (η4-1,3-diene)Fe(CO)3 complexes.

AB - The addition of reactive carbanions to (η4-1,3-diene)Fe(CO) 3 complexes at -78 °C and 25 °C produced putative homoallyl and allyl anion complexes, respectively. Reaction of the reactive intermediates with 2-(phenylsulfonyl)-3-phenyloxaziridine afforded nucleophilic substituted (η4-1,3-diene)Fe(CO)3 complexes.

KW - Davis reagent

KW - Diene

KW - Hydride

KW - Iron

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U2 - 10.1002/jccs.200300116

DO - 10.1002/jccs.200300116

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VL - 50

SP - 833

EP - 840

JO - Journal of the Chinese Chemical Society

JF - Journal of the Chinese Chemical Society

SN - 0009-4536

IS - 4

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