The vanadium kbetakalphaintensity ratios of some vanadium compounds

Chu Nan Chang; Chi Te Chen; Cheng Chieh Yen; Yin Hung Wu; Chiung Wu Su; Shih Kuan Chiou

doi:10.1088/0953-4075/27/21/017

The vanadium k_betak_alphaintensity ratios of some vanadium compounds

Chu Nan Chang, Chi Te Chen, Cheng Chieh Yen, Yin Hung Wu, Chiung Wu Su, Shih Kuan Chiou

Research output: Contribution to journal › Article › peer-review

42 Citations (Scopus)

Abstract

The vanadium K_beta/K_alphaintensity ratios of some simple vanadium compounds, VO, V₂O₃, VO₂, V₆O₁₃, V₂O₅, VN and VC have been measured by using a Si(Li) X-ray spectrometer. Strong covalent compounds in general have large vanadium K_beta/K_alphaintensity ratios which can be attributed to the non-diagram lines due to the band mixing between the metal and the ligands. For relatively weak covalent compounds the contribution from the change of the diagram line may have to be included.

Original language	English
Pages (from-to)	5251-5256
Number of pages	6
Journal	Journal of Physics B: Atomic, Molecular and Optical Physics
Volume	27
Issue number	21
DOIs	https://doi.org/10.1088/0953-4075/27/21/017
Publication status	Published - 1994 Nov 14
Externally published	Yes

ASJC Scopus subject areas

Atomic and Molecular Physics, and Optics
Condensed Matter Physics

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10.1088/0953-4075/27/21/017

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abstract = "The vanadium Kbeta/Kalphaintensity ratios of some simple vanadium compounds, VO, V2O3, VO2, V6O13, V2O5, VN and VC have been measured by using a Si(Li) X-ray spectrometer. Strong covalent compounds in general have large vanadium Kbeta/Kalphaintensity ratios which can be attributed to the non-diagram lines due to the band mixing between the metal and the ligands. For relatively weak covalent compounds the contribution from the change of the diagram line may have to be included.",

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AU - Su, Chiung Wu

AU - Chiou, Shih Kuan

PY - 1994/11/14

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AB - The vanadium Kbeta/Kalphaintensity ratios of some simple vanadium compounds, VO, V2O3, VO2, V6O13, V2O5, VN and VC have been measured by using a Si(Li) X-ray spectrometer. Strong covalent compounds in general have large vanadium Kbeta/Kalphaintensity ratios which can be attributed to the non-diagram lines due to the band mixing between the metal and the ligands. For relatively weak covalent compounds the contribution from the change of the diagram line may have to be included.

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The vanadium k_betak_alphaintensity ratios of some vanadium compounds

Abstract

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