The unusual paramagnetic mixed-metal carbonyl chalcogenide clusters: [E2Cr2Fe(CO)10]2- (E = Te, Se)

Minghuey Shieh; Ren Ling Chung; Chun Hsien Yu; Miao Hsing Hsu; Chia Hua Ho; Shie Ming Peng; Yi Hung Liu

doi:10.1021/ic034081m

The unusual paramagnetic mixed-metal carbonyl chalcogenide clusters: [E₂Cr₂Fe(CO)₁₀]^2- (E = Te, Se)

Minghuey Shieh^*, Ren Ling Chung, Chun Hsien Yu, Miao Hsing Hsu, Chia Hua Ho, Shie Ming Peng, Yi Hung Liu

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

21 Citations (Scopus)

Abstract

The rare examples of electron-rich mixed-metal carbonyl telluride and selenide clusters [E₂Cr₂Fe(CO)₁₀]^2- (E = Te, Se) have been demonstrated. These two novel carbonyl complexes exhibit the unusual paramagnetic behavior.

Original language	English
Pages (from-to)	5477-5479
Number of pages	3
Journal	Inorganic Chemistry
Volume	42
Issue number	18
DOIs	https://doi.org/10.1021/ic034081m
Publication status	Published - 2003 Sept 8

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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10.1021/ic034081m

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abstract = "The rare examples of electron-rich mixed-metal carbonyl telluride and selenide clusters [E2Cr2Fe(CO)10]2- (E = Te, Se) have been demonstrated. These two novel carbonyl complexes exhibit the unusual paramagnetic behavior.",

author = "Minghuey Shieh and Chung, {Ren Ling} and Yu, {Chun Hsien} and Hsu, {Miao Hsing} and Ho, {Chia Hua} and Peng, {Shie Ming} and Liu, {Yi Hung}",

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AU - Hsu, Miao Hsing

AU - Ho, Chia Hua

AU - Peng, Shie Ming

AU - Liu, Yi Hung

PY - 2003/9/8

Y1 - 2003/9/8

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The unusual paramagnetic mixed-metal carbonyl chalcogenide clusters: [E₂Cr₂Fe(CO)₁₀]^2- (E = Te, Se)

Abstract

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CCDC 197681: Experimental Crystal Structure Determination

CCDC 197682: Experimental Crystal Structure Determination

Cite this

The unusual paramagnetic mixed-metal carbonyl chalcogenide clusters: [E2Cr2Fe(CO)10]2- (E = Te, Se)

Abstract

ASJC Scopus subject areas

Access to Document

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CCDC 197681: Experimental Crystal Structure Determination

CCDC 197682: Experimental Crystal Structure Determination

Cite this

The unusual paramagnetic mixed-metal carbonyl chalcogenide clusters: [E₂Cr₂Fe(CO)₁₀]^2- (E = Te, Se)