The unusual paramagnetic mixed-metal carbonyl chalcogenide clusters: [E2Cr2Fe(CO)10]2- (E = Te, Se)

Minghuey Shieh, Ren Ling Chung, Chun Hsien Yu, Miao Hsing Hsu, Chia Hua Ho, Shie Ming Peng, Yi Hung Liu

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Abstract

The rare examples of electron-rich mixed-metal carbonyl telluride and selenide clusters [E2Cr2Fe(CO)10]2- (E = Te, Se) have been demonstrated. These two novel carbonyl complexes exhibit the unusual paramagnetic behavior.

Original languageEnglish
Pages (from-to)5477-5479
Number of pages3
JournalInorganic Chemistry
Volume42
Issue number18
DOIs
Publication statusPublished - 2003 Sep 8

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ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

Cite this

Shieh, M., Chung, R. L., Yu, C. H., Hsu, M. H., Ho, C. H., Peng, S. M., & Liu, Y. H. (2003). The unusual paramagnetic mixed-metal carbonyl chalcogenide clusters: [E2Cr2Fe(CO)10]2- (E = Te, Se). Inorganic Chemistry, 42(18), 5477-5479. https://doi.org/10.1021/ic034081m