The transition state of thermal organic reactions: Direct observation in real time

D. Hern Paik; Ding Shyue Yang; I. Ren Lee; Ahmed H. Zewail

doi:10.1002/anie.200453962

The transition state of thermal organic reactions: Direct observation in real time

D. Hern Paik^*
, Ding Shyue Yang
, I. Ren Lee
, Ahmed H. Zewail

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

A classic in physical organic chemistry, the inversion of cyclooctatetraene (COT), was studied with femtosecond resolution by negative-ion-beam techniques. The transition state for the thermal inversion was accessed directly by detachment of the electron from the planar COT^- ion.

Original language	English
Pages (from-to)	2830-2834
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	43
Issue number	21
DOIs	https://doi.org/10.1002/anie.200453962
Publication status	Published - 2004 May 17
Externally published	Yes

Keywords

Cyclooctatetraene
Femtochemistry
Photodetachment
Transition states
Wave-packet dynamics

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1002/anie.200453962

Cite this

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title = "The transition state of thermal organic reactions: Direct observation in real time",

abstract = "A classic in physical organic chemistry, the inversion of cyclooctatetraene (COT), was studied with femtosecond resolution by negative-ion-beam techniques. The transition state for the thermal inversion was accessed directly by detachment of the electron from the planar COT- ion.",

keywords = "Cyclooctatetraene, Femtochemistry, Photodetachment, Transition states, Wave-packet dynamics",

author = "Paik, \{D. Hern\} and Yang, \{Ding Shyue\} and Lee, \{I. Ren\} and Zewail, \{Ahmed H.\}",

year = "2004",

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T2 - Direct observation in real time

AU - Paik, D. Hern

AU - Yang, Ding Shyue

AU - Lee, I. Ren

AU - Zewail, Ahmed H.

PY - 2004/5/17

Y1 - 2004/5/17

N2 - A classic in physical organic chemistry, the inversion of cyclooctatetraene (COT), was studied with femtosecond resolution by negative-ion-beam techniques. The transition state for the thermal inversion was accessed directly by detachment of the electron from the planar COT- ion.

AB - A classic in physical organic chemistry, the inversion of cyclooctatetraene (COT), was studied with femtosecond resolution by negative-ion-beam techniques. The transition state for the thermal inversion was accessed directly by detachment of the electron from the planar COT- ion.

KW - Cyclooctatetraene

KW - Femtochemistry

KW - Photodetachment

KW - Transition states

KW - Wave-packet dynamics

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AN - SCOPUS:4544253303

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 21

ER -

The transition state of thermal organic reactions: Direct observation in real time

Abstract

Keywords

ASJC Scopus subject areas

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