The role of Fe-Ti oxide crystallization in the formation of A-type granitoids with implications for the Daly gap: An example from the Permian Baima igneous complex, SW China

J. Gregory Shellnutt, Mei Fu Zhou, Georg F. Zellmer

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102 Citations (Scopus)

Abstract

The Baima igneous complex (BIC) is a member of the Permian Emeishan large igneous province, SW China, and is composed of a layered gabbroic unit and an isotropic syenitic unit. The gabbroic unit consists of four distinct zones, 1) lower cumulate zone, 2) massive Fe-Ti-V oxide ore zone, 3) olivine gabbro zone and 4) upper gabbro zone. SHRIMP zircon U-Pb dating results yield an age of 261 ± 2 Ma for the gabbroic unit, contemporaneous with the spatially associated syenitic unit. The gabbroic rocks show slightly LREE enriched patterns with (La/Yb)N values between 1.6 and 12.1 and positive Eu anomalies (Eu/Eu* = 1.1-3.6). In contrast, the syenites display stronger enrichments of LREE (La/YbN = 6.8-51.3) and negative Eu anomalies (Eu/Eu* = 0.3-1.1). Rocks of the syenitic unit are chemically similar to the ferroan alkalic A-type granitoids (K2O/Na2O = 0.58-0.80, FeOt/(FeOt +MgO) = 0.80-0.91) and have a within-plate geochemical signature. Both units have similar trace element ratios (Zr/Nb, Th/U, Ni/Co, Cu/Ni, Hf/Ta and Zn/Ga) resembling an ocean-island basalt source. The εNd(T) values for the gabbroic unit (εNd(T) = + 1.6-+ 4.2) and syenitic unit (εNd(T) = + 2.5-+ 3.2) are within the range of the high-Ti Emeishan flood basalts. The geochemical and geochronological data indicate that the gabbroic and syenitic units are comagmatic and cogenetic. Geochemical modeling suggests that the two units originated by fractional crystallization of a common parental magma that resembles the high-Ti Emeishan flood basalts. The formation of the two units by fractional crystallization was likely responsible for the enrichment of Fe-Ti-V oxide minerals in the gabbroic unit and thus the development of the Daly gap. The results of this study indicate that silica saturated peralkaline A-type granitoids can be formed by fractionation of mantle derived mafic magmas.

Original languageEnglish
Pages (from-to)204-217
Number of pages14
JournalChemical Geology
Volume259
Issue number3-4
DOIs
Publication statusPublished - 2009 Feb 25

Fingerprint

Crystallization
Oxides
Permian
crystallization
oxide
Rocks
Oxide minerals
flood basalt
fractional crystallization
gabbro
Trace Elements
Fractionation
Silicon Dioxide
Ores
anomaly
large igneous province
ocean island basalt
cumulate
rock
olivine

Keywords

  • A-type granitoid
  • Daly gap
  • Emeishan large igneous province
  • Fe-Ti-V deposit
  • Layered mafic intrusion
  • Permian
  • SW China

ASJC Scopus subject areas

  • Geology
  • Geochemistry and Petrology

Cite this

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title = "The role of Fe-Ti oxide crystallization in the formation of A-type granitoids with implications for the Daly gap: An example from the Permian Baima igneous complex, SW China",
abstract = "The Baima igneous complex (BIC) is a member of the Permian Emeishan large igneous province, SW China, and is composed of a layered gabbroic unit and an isotropic syenitic unit. The gabbroic unit consists of four distinct zones, 1) lower cumulate zone, 2) massive Fe-Ti-V oxide ore zone, 3) olivine gabbro zone and 4) upper gabbro zone. SHRIMP zircon U-Pb dating results yield an age of 261 ± 2 Ma for the gabbroic unit, contemporaneous with the spatially associated syenitic unit. The gabbroic rocks show slightly LREE enriched patterns with (La/Yb)N values between 1.6 and 12.1 and positive Eu anomalies (Eu/Eu* = 1.1-3.6). In contrast, the syenites display stronger enrichments of LREE (La/YbN = 6.8-51.3) and negative Eu anomalies (Eu/Eu* = 0.3-1.1). Rocks of the syenitic unit are chemically similar to the ferroan alkalic A-type granitoids (K2O/Na2O = 0.58-0.80, FeOt/(FeOt +MgO) = 0.80-0.91) and have a within-plate geochemical signature. Both units have similar trace element ratios (Zr/Nb, Th/U, Ni/Co, Cu/Ni, Hf/Ta and Zn/Ga) resembling an ocean-island basalt source. The εNd(T) values for the gabbroic unit (εNd(T) = + 1.6-+ 4.2) and syenitic unit (εNd(T) = + 2.5-+ 3.2) are within the range of the high-Ti Emeishan flood basalts. The geochemical and geochronological data indicate that the gabbroic and syenitic units are comagmatic and cogenetic. Geochemical modeling suggests that the two units originated by fractional crystallization of a common parental magma that resembles the high-Ti Emeishan flood basalts. The formation of the two units by fractional crystallization was likely responsible for the enrichment of Fe-Ti-V oxide minerals in the gabbroic unit and thus the development of the Daly gap. The results of this study indicate that silica saturated peralkaline A-type granitoids can be formed by fractionation of mantle derived mafic magmas.",
keywords = "A-type granitoid, Daly gap, Emeishan large igneous province, Fe-Ti-V deposit, Layered mafic intrusion, Permian, SW China",
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T1 - The role of Fe-Ti oxide crystallization in the formation of A-type granitoids with implications for the Daly gap

T2 - An example from the Permian Baima igneous complex, SW China

AU - Shellnutt, J. Gregory

AU - Zhou, Mei Fu

AU - Zellmer, Georg F.

PY - 2009/2/25

Y1 - 2009/2/25

N2 - The Baima igneous complex (BIC) is a member of the Permian Emeishan large igneous province, SW China, and is composed of a layered gabbroic unit and an isotropic syenitic unit. The gabbroic unit consists of four distinct zones, 1) lower cumulate zone, 2) massive Fe-Ti-V oxide ore zone, 3) olivine gabbro zone and 4) upper gabbro zone. SHRIMP zircon U-Pb dating results yield an age of 261 ± 2 Ma for the gabbroic unit, contemporaneous with the spatially associated syenitic unit. The gabbroic rocks show slightly LREE enriched patterns with (La/Yb)N values between 1.6 and 12.1 and positive Eu anomalies (Eu/Eu* = 1.1-3.6). In contrast, the syenites display stronger enrichments of LREE (La/YbN = 6.8-51.3) and negative Eu anomalies (Eu/Eu* = 0.3-1.1). Rocks of the syenitic unit are chemically similar to the ferroan alkalic A-type granitoids (K2O/Na2O = 0.58-0.80, FeOt/(FeOt +MgO) = 0.80-0.91) and have a within-plate geochemical signature. Both units have similar trace element ratios (Zr/Nb, Th/U, Ni/Co, Cu/Ni, Hf/Ta and Zn/Ga) resembling an ocean-island basalt source. The εNd(T) values for the gabbroic unit (εNd(T) = + 1.6-+ 4.2) and syenitic unit (εNd(T) = + 2.5-+ 3.2) are within the range of the high-Ti Emeishan flood basalts. The geochemical and geochronological data indicate that the gabbroic and syenitic units are comagmatic and cogenetic. Geochemical modeling suggests that the two units originated by fractional crystallization of a common parental magma that resembles the high-Ti Emeishan flood basalts. The formation of the two units by fractional crystallization was likely responsible for the enrichment of Fe-Ti-V oxide minerals in the gabbroic unit and thus the development of the Daly gap. The results of this study indicate that silica saturated peralkaline A-type granitoids can be formed by fractionation of mantle derived mafic magmas.

AB - The Baima igneous complex (BIC) is a member of the Permian Emeishan large igneous province, SW China, and is composed of a layered gabbroic unit and an isotropic syenitic unit. The gabbroic unit consists of four distinct zones, 1) lower cumulate zone, 2) massive Fe-Ti-V oxide ore zone, 3) olivine gabbro zone and 4) upper gabbro zone. SHRIMP zircon U-Pb dating results yield an age of 261 ± 2 Ma for the gabbroic unit, contemporaneous with the spatially associated syenitic unit. The gabbroic rocks show slightly LREE enriched patterns with (La/Yb)N values between 1.6 and 12.1 and positive Eu anomalies (Eu/Eu* = 1.1-3.6). In contrast, the syenites display stronger enrichments of LREE (La/YbN = 6.8-51.3) and negative Eu anomalies (Eu/Eu* = 0.3-1.1). Rocks of the syenitic unit are chemically similar to the ferroan alkalic A-type granitoids (K2O/Na2O = 0.58-0.80, FeOt/(FeOt +MgO) = 0.80-0.91) and have a within-plate geochemical signature. Both units have similar trace element ratios (Zr/Nb, Th/U, Ni/Co, Cu/Ni, Hf/Ta and Zn/Ga) resembling an ocean-island basalt source. The εNd(T) values for the gabbroic unit (εNd(T) = + 1.6-+ 4.2) and syenitic unit (εNd(T) = + 2.5-+ 3.2) are within the range of the high-Ti Emeishan flood basalts. The geochemical and geochronological data indicate that the gabbroic and syenitic units are comagmatic and cogenetic. Geochemical modeling suggests that the two units originated by fractional crystallization of a common parental magma that resembles the high-Ti Emeishan flood basalts. The formation of the two units by fractional crystallization was likely responsible for the enrichment of Fe-Ti-V oxide minerals in the gabbroic unit and thus the development of the Daly gap. The results of this study indicate that silica saturated peralkaline A-type granitoids can be formed by fractionation of mantle derived mafic magmas.

KW - A-type granitoid

KW - Daly gap

KW - Emeishan large igneous province

KW - Fe-Ti-V deposit

KW - Layered mafic intrusion

KW - Permian

KW - SW China

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