The Mechanism of PEDOT: PSS Films with Organic Additives

Shui Yang Lien; Po Chen Lin; Wen Ray Chen; Chuan Hsi Liu; Kuan Wei Lee; Na Fu Wang; Chien Jung Huang

doi:10.3390/cryst12081109

The Mechanism of PEDOT: PSS Films with Organic Additives

Shui Yang Lien
, Po Chen Lin
, Wen Ray Chen
, Chuan Hsi Liu^*
, Kuan Wei Lee
, Na Fu Wang
, Chien Jung Huang^*

^*Corresponding author for this work

Department of Mechatronic Engineering

Research output: Contribution to journal › Article › peer-review

21 Citations (Scopus)

Abstract

This article demonstrates changes in the structures of poly (3,4-ethylene dioxythiophene): polystyrene sulfonate (PEDOT: PSS) with the addition of organic additives. The mechanisms of PEDOT: PSS are analyzed using X-ray photoelectron spectroscopy (XPS), cross-sectional images obtained from scanning electron microscopy (SEM), and contact angles. In this paper, a bond-breaking reaction and phase separation are successfully found to occur between PEDOT: PSS molecules and the organic additives. Our research also finds that this bond-breaking reaction and phase separation exist in the PEDOT: PSS–sorbitol–maltitol film at the same time. The addition of organic additives will improve the optical properties and the moisture stability of PEDOT: PSS films.

Original language	English
Article number	1109
Journal	Crystals
Volume	12
Issue number	8
DOIs	https://doi.org/10.3390/cryst12081109
Publication status	Published - 2022 Aug

Keywords

PEDOT: PSS
bond-breaking reaction
organic additive
phase separation

ASJC Scopus subject areas

General Chemical Engineering
General Materials Science
Condensed Matter Physics
Inorganic Chemistry

Access to Document

10.3390/cryst12081109

Cite this

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title = "The Mechanism of PEDOT: PSS Films with Organic Additives",

abstract = "This article demonstrates changes in the structures of poly (3,4-ethylene dioxythiophene): polystyrene sulfonate (PEDOT: PSS) with the addition of organic additives. The mechanisms of PEDOT: PSS are analyzed using X-ray photoelectron spectroscopy (XPS), cross-sectional images obtained from scanning electron microscopy (SEM), and contact angles. In this paper, a bond-breaking reaction and phase separation are successfully found to occur between PEDOT: PSS molecules and the organic additives. Our research also finds that this bond-breaking reaction and phase separation exist in the PEDOT: PSS–sorbitol–maltitol film at the same time. The addition of organic additives will improve the optical properties and the moisture stability of PEDOT: PSS films.",

keywords = "PEDOT: PSS, bond-breaking reaction, organic additive, phase separation",

author = "Lien, \{Shui Yang\} and Lin, \{Po Chen\} and Chen, \{Wen Ray\} and Liu, \{Chuan Hsi\} and Lee, \{Kuan Wei\} and Wang, \{Na Fu\} and Huang, \{Chien Jung\}",

note = "Publisher Copyright: {\textcopyright} 2022 by the authors.",

year = "2022",

month = aug,

doi = "10.3390/cryst12081109",

language = "English",

volume = "12",

journal = "Crystals",

issn = "2073-4352",

publisher = "Multidisciplinary Digital Publishing Institute (MDPI)",

number = "8",

}

TY - JOUR

T1 - The Mechanism of PEDOT

T2 - PSS Films with Organic Additives

AU - Lien, Shui Yang

AU - Lin, Po Chen

AU - Chen, Wen Ray

AU - Liu, Chuan Hsi

AU - Lee, Kuan Wei

AU - Wang, Na Fu

AU - Huang, Chien Jung

PY - 2022/8

Y1 - 2022/8

N2 - This article demonstrates changes in the structures of poly (3,4-ethylene dioxythiophene): polystyrene sulfonate (PEDOT: PSS) with the addition of organic additives. The mechanisms of PEDOT: PSS are analyzed using X-ray photoelectron spectroscopy (XPS), cross-sectional images obtained from scanning electron microscopy (SEM), and contact angles. In this paper, a bond-breaking reaction and phase separation are successfully found to occur between PEDOT: PSS molecules and the organic additives. Our research also finds that this bond-breaking reaction and phase separation exist in the PEDOT: PSS–sorbitol–maltitol film at the same time. The addition of organic additives will improve the optical properties and the moisture stability of PEDOT: PSS films.

AB - This article demonstrates changes in the structures of poly (3,4-ethylene dioxythiophene): polystyrene sulfonate (PEDOT: PSS) with the addition of organic additives. The mechanisms of PEDOT: PSS are analyzed using X-ray photoelectron spectroscopy (XPS), cross-sectional images obtained from scanning electron microscopy (SEM), and contact angles. In this paper, a bond-breaking reaction and phase separation are successfully found to occur between PEDOT: PSS molecules and the organic additives. Our research also finds that this bond-breaking reaction and phase separation exist in the PEDOT: PSS–sorbitol–maltitol film at the same time. The addition of organic additives will improve the optical properties and the moisture stability of PEDOT: PSS films.

KW - PEDOT: PSS

KW - bond-breaking reaction

KW - organic additive

KW - phase separation

UR - https://www.scopus.com/pages/publications/85137391250

UR - https://www.scopus.com/pages/publications/85137391250#tab=citedBy

U2 - 10.3390/cryst12081109

DO - 10.3390/cryst12081109

M3 - Article

AN - SCOPUS:85137391250

SN - 2073-4352

VL - 12

JO - Crystals

JF - Crystals

IS - 8

M1 - 1109

ER -

The Mechanism of PEDOT: PSS Films with Organic Additives

Abstract

Keywords

ASJC Scopus subject areas

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